Synthesis, crystal structure and thermochemical study on a novel ternary coordination compound [Bi(C7H5O3)(3)C12H8N2]
文献类型：期刊论文
| 作者 | Xiao, Sheng-Xiong1,2; Zheng, Xiao-Fang1; Li, Wen-Juan1; Li, Chuan-Hua1,2; Jiang, Shu-Li1; Lu, Liang1; Li, Xu1,2; Han, Bu-Xing3; Li, Qiang-Guo1,2 |
| 刊名 | JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
 |
| 出版日期 | 2015-06-01 |
| 卷号 | 120期号:3页码:1859-1865 |
| 关键词 | Bismuth complex o-Hydroxybenzoic acid o-Phenanthroline Crystal structure Standard molar enthalpy of formation |
| 英文摘要 | A new ternary bismuth complex [Bi(C7H5O3)(3)C12H8N2] (C7H6O3, o-hydroxybenzoic acid; C12H8N2, 1,10-phenanthroline monohydrate) and its crystal were prepared and characterized. The results showed that the crystal is triclinic, space group P A << with a = 10.184(2) , b = 11.807(2) , c = 12.893(3) , alpha = 76.81(3)A degrees, beta = 68.79(3)A degrees, gamma = 80.85(3)A degrees, Z = 2, Dc = 1.891 g cm(-3), F(000) = 776. The crystal contains a mononuclear molecule. Bi3+ is eight-coordinated by three bidentate chelating carboxylic groups and one o-phenanthroline molecule; C7H6O3 coordinated with Bi3+ in the form of carboxylate; the two nitrogen atoms of C12H8N2 are bidentate-coordinated with Bi3+ forming a chelate ring. At 298.15 K, the standard molar enthalpy of formation of the title complex was estimated to be Delta (f) H (m) (I similar to) [Bi(C7H5O3)(3)C12H8N2 (s), 298.15 K] = -(303.99 +/- A 4.95) kJ mol(-1). |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/28072]  |
| 专题 | 化学研究所_胶体、界面与化学热力学实验室 |
| 作者单位 | 1.Xiangnan Univ, Dept Chem & Life Sci, Chenzhou 423043, Hunan, Peoples R China 2.Hunan Prov Key Lab Rare Precious Met Cpds & Appli, Chenzhou 423043, Hunan, Peoples R China 3.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiao, Sheng-Xiong,Zheng, Xiao-Fang,Li, Wen-Juan,et al. Synthesis, crystal structure and thermochemical study on a novel ternary coordination compound [Bi(C7H5O3)(3)C12H8N2][J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2015,120(3):1859-1865. |
| APA | Xiao, Sheng-Xiong.,Zheng, Xiao-Fang.,Li, Wen-Juan.,Li, Chuan-Hua.,Jiang, Shu-Li.,...&Li, Qiang-Guo.(2015).Synthesis, crystal structure and thermochemical study on a novel ternary coordination compound [Bi(C7H5O3)(3)C12H8N2].JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,120(3),1859-1865. |
| MLA | Xiao, Sheng-Xiong,et al."Synthesis, crystal structure and thermochemical study on a novel ternary coordination compound [Bi(C7H5O3)(3)C12H8N2]".JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY 120.3(2015):1859-1865. |
入库方式： OAI收割
来源：化学研究所
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