Reactive organogels based on isoxazole esters: alkali metal ions selective gelation and crystallization
文献类型：期刊论文
| 作者 | Jin, Qingxian1; Li, Jing1,2; Zhang, Li2; Fang, Shaoming1; Liu, Minghua2 |
| 刊名 | CRYSTENGCOMM
 |
| 出版日期 | 2015 |
| 卷号 | 17期号:42页码:8058-8063 |
| 英文摘要 | A series of simple ester molecules containing an isoxazole moiety were found to form instant organogels at room temperature in the presence of NaOH without the heating-cooling cycle used for conventional supramolecular gels. The gelation process was triggered due to the hydrolysis of the isoxazole esters and occurred selectively with Na+. When LiOH, NaOH and KOH were separately introduced into the methanol solutions of the isoxazole esters, the solution remained as a solution, transformed to a organogel and a crystal, respectively. With the help of a study on the phase behavior of the corresponding isoxazole acid in the presence of the alkali bases, it was revealed that pi-pi stacking of the isoxazole moiety and the ionic interaction between the carboxylates and Na+ are the main driving forces for the self-assembly and the organogelation. The size of the alkali metal ions will subtly affect the gelation, with the Li+ and K+ ions leading to solution and crystallization, respectively. These results have provided an insight into the balance between the solution, gelation and crystallization with subtle molecular variations. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/29130]  |
| 专题 | 化学研究所_胶体、界面与化学热力学实验室 |
| 作者单位 | 1.Zhengzhou Univ Light Ind, Henan Prov Key Lab Surface & Interface Sci, Zhengzhou 450002, Henan, Peoples R China 2.Chinese Acad Sci, Inst Chem, CAS Key Lab Colloid Interface & Chem Thermodynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jin, Qingxian,Li, Jing,Zhang, Li,et al. Reactive organogels based on isoxazole esters: alkali metal ions selective gelation and crystallization[J]. CRYSTENGCOMM,2015,17(42):8058-8063. |
| APA | Jin, Qingxian,Li, Jing,Zhang, Li,Fang, Shaoming,&Liu, Minghua.(2015).Reactive organogels based on isoxazole esters: alkali metal ions selective gelation and crystallization.CRYSTENGCOMM,17(42),8058-8063. |
| MLA | Jin, Qingxian,et al."Reactive organogels based on isoxazole esters: alkali metal ions selective gelation and crystallization".CRYSTENGCOMM 17.42(2015):8058-8063. |
入库方式： OAI收割
来源：化学研究所
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