Cooperative catalysis of Pt/C and acid resin for the production of 2,5-dimethyltetrahydrofuran from biomass derived 2,5-hexanedione under mild conditions
文献类型：期刊论文
| 作者 | Zhou, Huacong1,2; Song, Jinliang1; Meng, Qinglei1; He, Zhenhong1; Jiang, Zhiwei1; Zhou, Baowen1; Liu, Huizhen1; Han, Buxing1 |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2016 |
| 卷号 | 18期号:1页码:220-225 |
| 英文摘要 | Conversion of biomass into 2,5-dimethyltetrahydrofuran (DMTHF), an excellent fuel additive, solvent, and industrial intermediate, is an important reaction in green chemistry. In this work, different combinations of supported metal catalysts and solid acids were investigated for the synthesis of DMTHF from biomass derived diketone (2,5-hexanedione, 2,5-HD). The results showed that commercial Pt/C and solid acid Amberlite (R) IR-120H had an excellent cooperative effect on the reaction. 2,5-HD could be converted into DMTHF with a yield up to 99% under milder conditions. Further experiments indicated that 2,5-hexanediol (2,5-HDO) is a key intermediate in the reaction. The catalyst system could be facilely recovered due to the heterogeneity and reused several times without notable change in the performance. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/29527]  |
| 专题 | 化学研究所_胶体、界面与化学热力学实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Inner Mongolia Univ Technol, Chem Engn Coll, Hohhot 010051, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Huacong,Song, Jinliang,Meng, Qinglei,et al. Cooperative catalysis of Pt/C and acid resin for the production of 2,5-dimethyltetrahydrofuran from biomass derived 2,5-hexanedione under mild conditions[J]. GREEN CHEMISTRY,2016,18(1):220-225. |
| APA | Zhou, Huacong.,Song, Jinliang.,Meng, Qinglei.,He, Zhenhong.,Jiang, Zhiwei.,...&Han, Buxing.(2016).Cooperative catalysis of Pt/C and acid resin for the production of 2,5-dimethyltetrahydrofuran from biomass derived 2,5-hexanedione under mild conditions.GREEN CHEMISTRY,18(1),220-225. |
| MLA | Zhou, Huacong,et al."Cooperative catalysis of Pt/C and acid resin for the production of 2,5-dimethyltetrahydrofuran from biomass derived 2,5-hexanedione under mild conditions".GREEN CHEMISTRY 18.1(2016):220-225. |
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来源：化学研究所
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