中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Water-alkane interface promotes the formation of metal-organic frameworks

文献类型:期刊论文

作者Ma, Xue; Zhang, Jianling; Peng, Li; Sang, Xinxin; Liu, Chengcheng; Jiang, Long; Han, Buxing; Zhang, Bingxing; Yang, Guanying
刊名MICROPOROUS AND MESOPOROUS MATERIALS
出版日期2016-01-15
卷号220页码:270-274
关键词Metal-organic framework Water-alkane interface Formation Porosity Hydrostability
英文摘要To develop facile, rapid and low-energy route for metal-organic framework (MOF) formation is of great importance. Here a water-alkane interface strategy was proposed for the MOF formation at room temperature. The content and molecular structure of alkane phase were found to have remarkable effect on regulating the porosity properties of MOFs. For example, the MOF synthesized in 1:1 (v/v) water/n-hexane mixture has the largest BET surface area (1474.1 m(2)/g) and total pore volume (0.7030 cm(3)/g). The mechanism was discussed from the competitive adsorption of water and alkane in the micropores of MOF building blocks during formation process. (C) 2015 Elsevier Inc. All rights reserved.
收录类别SCI
语种英语
公开日期2016-05-09
源URL[http://ir.iccas.ac.cn/handle/121111/29544]  
专题化学研究所_胶体、界面与化学热力学实验室
作者单位Chinese Acad Sci, Inst Chem, CAS Key Lab Colloid & Interface & Thermodynam, Beijing Natl Lab Mol Sci, Beijing 100864, Peoples R China
推荐引用方式
GB/T 7714
Ma, Xue,Zhang, Jianling,Peng, Li,et al. Water-alkane interface promotes the formation of metal-organic frameworks[J]. MICROPOROUS AND MESOPOROUS MATERIALS,2016,220:270-274.
APA Ma, Xue.,Zhang, Jianling.,Peng, Li.,Sang, Xinxin.,Liu, Chengcheng.,...&Yang, Guanying.(2016).Water-alkane interface promotes the formation of metal-organic frameworks.MICROPOROUS AND MESOPOROUS MATERIALS,220,270-274.
MLA Ma, Xue,et al."Water-alkane interface promotes the formation of metal-organic frameworks".MICROPOROUS AND MESOPOROUS MATERIALS 220(2016):270-274.

入库方式: OAI收割

来源:化学研究所

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