Synthesis of Supported Ultrafine Non-noble Subnanometer-Scale Metal Particles Derived from Metal-Organic Frameworks as Highly Efficient Heterogeneous Catalysts
文献类型：期刊论文
| 作者 | Kang, Xinchen; Liu, Huizhen; Hou, Minqiang; Sun, Xiaofu; Han, Hongling; Jiang, Tao; Zhang, Zhaofu; Han, Buxing |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2016-01-18 |
| 卷号 | 55期号:3页码:1080-1084 |
| 关键词 | benzene hydrogenation metal-organic frameworks non-noble metals supported catalysts ultrafine nanoparticles |
| 英文摘要 | The properties of supported non-noble metal particles with a size of less than 1nm are unknown because their synthesis is a challenge. A strategy has now been created to immobilize ultrafine non-noble metal particles on supports using metal-organic frameworks (MOFs) as metal precursors. Ni/SiO2 and Co/SiO2 catalysts were synthesized with an average metal particle size of 0.9nm. The metal nanoparticles were immobilized uniformly on the support with a metal loading of about 20wt%. Interestingly, the ultrafine non-noble metal particles exhibited very high activity for liquid-phase hydrogenation of benzene to cyclohexane even at 80 degrees C, while Ni/SiO2 with larger Ni particles fabricated by a conventional method was not active under the same conditions. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/29774]  |
| 专题 | 化学研究所_胶体、界面与化学热力学实验室 |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100864, Peoples R China |
| 推荐引用方式 GB/T 7714 | Kang, Xinchen,Liu, Huizhen,Hou, Minqiang,et al. Synthesis of Supported Ultrafine Non-noble Subnanometer-Scale Metal Particles Derived from Metal-Organic Frameworks as Highly Efficient Heterogeneous Catalysts[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2016,55(3):1080-1084. |
| APA | Kang, Xinchen.,Liu, Huizhen.,Hou, Minqiang.,Sun, Xiaofu.,Han, Hongling.,...&Han, Buxing.(2016).Synthesis of Supported Ultrafine Non-noble Subnanometer-Scale Metal Particles Derived from Metal-Organic Frameworks as Highly Efficient Heterogeneous Catalysts.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,55(3),1080-1084. |
| MLA | Kang, Xinchen,et al."Synthesis of Supported Ultrafine Non-noble Subnanometer-Scale Metal Particles Derived from Metal-Organic Frameworks as Highly Efficient Heterogeneous Catalysts".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55.3(2016):1080-1084. |
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来源：化学研究所
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