Hydrogen-Bonding-Mediated Synthesis of Atomically Thin TiO2 Films with Exposed (001) Facets and Applications in Fast Lithium Insertion/Extraction
文献类型：期刊论文
| 作者 | Zhang, Hongye1; Yang, Zhenzhen1; Gan, Wei2; Zhao, Yanfei1; Yu, Bo1; Xu, Huanjun1; Ma, Zhishuang1; Hao, Leiduan1; Chen, Dechao2; Miao, Shiding2 |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2015-10-05 |
| 卷号 | 21期号:41页码:14608-14613 |
| 关键词 | hydrogen bonds insertion lithium nanostructures synergistic effect |
| 英文摘要 | Ultrathin two-dimensional (2D) crystalline materials show high specific surface area (SA) of high energy (HE) facets, imparting a significant improvement in their performances. Herein we report a novel route to synthesize TiO2 nanofilms (NFs) with atomic thickness (<2.0 nm) through a solvothermal reaction mediated by the hydrogen-bonding networks constructed by hydroquinone (HQ). The resultant TiO2 NFs have nearly 100% exposed (001) facets and give extremely high SA up to 487 m(2)g(-1). The synergistic effect of HQ and choline chloride plays a vital role in the formation of TiO2 NFs and in the exposure of HE (001) facets. (B)ecause of its ultrathin feature and exposed (001) facet, the N-2-annealled TiO2 NFs showed fast kinetics of lithium insertion/extraction, demonstrating foreseeable applications in the energy storage. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/29141]  |
| 专题 | 化学研究所_胶体、界面与化学热力学实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China 2.Hefei Univ Technol, Sch Chem & Chem Engn, Hefei 230009, Anhui, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Hongye,Yang, Zhenzhen,Gan, Wei,et al. Hydrogen-Bonding-Mediated Synthesis of Atomically Thin TiO2 Films with Exposed (001) Facets and Applications in Fast Lithium Insertion/Extraction[J]. CHEMISTRY-A EUROPEAN JOURNAL,2015,21(41):14608-14613. |
| APA | Zhang, Hongye.,Yang, Zhenzhen.,Gan, Wei.,Zhao, Yanfei.,Yu, Bo.,...&Liu, Zhimin.(2015).Hydrogen-Bonding-Mediated Synthesis of Atomically Thin TiO2 Films with Exposed (001) Facets and Applications in Fast Lithium Insertion/Extraction.CHEMISTRY-A EUROPEAN JOURNAL,21(41),14608-14613. |
| MLA | Zhang, Hongye,et al."Hydrogen-Bonding-Mediated Synthesis of Atomically Thin TiO2 Films with Exposed (001) Facets and Applications in Fast Lithium Insertion/Extraction".CHEMISTRY-A EUROPEAN JOURNAL 21.41(2015):14608-14613. |
入库方式： OAI收割
来源：化学研究所
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