Synthesis and photovoltaic properties of two new alkoxylphenyl substituted thieno[2,3-f]benzofuran based polymers
文献类型：期刊论文
| 作者 | Qiu, Beibei1; Cui, Ruili1; Yuan, Jun1; Peng, Hongjian1; Zhang, Zhiguo2; Li, Yongfang2; Zou, Yingping1 |
| 刊名 | PHYSICAL CHEMISTRY CHEMICAL PHYSICS
 |
| 出版日期 | 2015 |
| 卷号 | 17期号:27页码:17592-17600 |
| 英文摘要 | Two new alkoxylphenyl substituted thieno[2,3-f] benzofuran (TBFP)-based polymers (PTBFP-BT and PTBFP-BO) were designed and synthesized. Their structures were verified by nuclear magnetic resonance (NMR) spectroscopy, the molecular weights were determined by gel permeation chromatography (GPC) and the thermal properties were investigated by thermogravimetric analysis (TGA). The two polymers showed similar UV-Vis absorption spectra with a broad and strong absorption band from 300-750 nm in solid state. The resulting copolymers exhibited relatively deep highest occupied molecular orbital (HOMO) energy levels (-5.47 and -5.61 eV) for PTBFP-BT and PTBFP-BO, respectively. The device fabricated with PTBFP-BT: PC71BM (1 : 2) showed better balanced hole and electron mobility of 2.49 x 10(-4) cm(2) V-1 s(-1) and 9.12 x 10(-4) cm(2) V-1 s(-1), respectively, than those of PTBFP-BO based devices. The polymer solar cells (PSCs), based on the single layer device structure of ITO/PEDOT:PSS/PTBFP-BT: PC71BM (1 : 2, w/w)/ZrAcac/Al with 3 vol% 1,8-diiodooctane (DIO) as additive, showed a relatively high power conversion efficiency (PCE) of 6% under the illumination of AM 1.5G, 100 mW cm(-2), with a high fill factor (FF) of 0.69. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/27819]  |
| 专题 | 化学研究所_有机固体实验室 |
| 作者单位 | 1.Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qiu, Beibei,Cui, Ruili,Yuan, Jun,et al. Synthesis and photovoltaic properties of two new alkoxylphenyl substituted thieno[2,3-f]benzofuran based polymers[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2015,17(27):17592-17600. |
| APA | Qiu, Beibei.,Cui, Ruili.,Yuan, Jun.,Peng, Hongjian.,Zhang, Zhiguo.,...&Zou, Yingping.(2015).Synthesis and photovoltaic properties of two new alkoxylphenyl substituted thieno[2,3-f]benzofuran based polymers.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,17(27),17592-17600. |
| MLA | Qiu, Beibei,et al."Synthesis and photovoltaic properties of two new alkoxylphenyl substituted thieno[2,3-f]benzofuran based polymers".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 17.27(2015):17592-17600. |
入库方式： OAI收割
来源：化学研究所
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