Modulating carrier transfer ability-linker effect on thieno[3,4-c]pyrrole-4,6-dione based conjugated polymers
文献类型：期刊论文
| 作者 | Qing, Wanmei1,2; Liu, Zitong3; Yang, Sifen3; Tan, Luxi2; Yang, Yang3; Zhang, Daijun2; Li, Jing2 |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2015 |
| 卷号 | 5期号:69页码:55619-55624 |
| 英文摘要 | Three conjugated copolymers Q1, Q2 and Q3 were developed based on thieno[3,4-c]pyrrole-4,6-dione (TPD) and two thiophene units. While Q1 was synthesized through direct linkage, Q2 and Q3 were constructed via introduction of a vinylene and ethynylene pi-spacer between two thiophene groups. Electrochemical and UV-vis absorption studies as well as theoretical calculations show that the LUMO energy of Q3 is lower than Q1, Q2 while Q2 possesses the narrowest bandgap. OFET devices based on thin-films of Q1 and Q2 can be easily fabricated through a solution-process with conventional techniques, while OFET devices based on thin-films of Q3 are fabricated by drop-casting. Q1 and Q2 showed maximum hole mobilities of 2.2 x 10(-3) cm(2) V-1 s(-1) and 0.01 cm(2) V-1 s(-1), respectively. Owing to the electron-withdrawing effect of the ethynylene group, Q3 based OFET devices exhibit a clear ambipolar semiconducting property in air conditions, with a maximum hole and electron mobility of 1.2 x 10(-6) cm(2) V-1 s(-1) and 0.6 x 10(-6) cm(2) V-1 s(-1), respectively. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/27869]  |
| 专题 | 化学研究所_有机固体实验室 |
| 作者单位 | 1.Chongqing Univ, Dept Chem Engn, Chongqing 400030, Peoples R China 2.Chinese Acad Sci, Chongqing Inst Green & Intelligent Technol, Chongqing 400714, Peoples R China 3.Chinese Acad Sci, Inst Chem, CAS Key Labs Organ Solids, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qing, Wanmei,Liu, Zitong,Yang, Sifen,et al. Modulating carrier transfer ability-linker effect on thieno[3,4-c]pyrrole-4,6-dione based conjugated polymers[J]. RSC ADVANCES,2015,5(69):55619-55624. |
| APA | Qing, Wanmei.,Liu, Zitong.,Yang, Sifen.,Tan, Luxi.,Yang, Yang.,...&Li, Jing.(2015).Modulating carrier transfer ability-linker effect on thieno[3,4-c]pyrrole-4,6-dione based conjugated polymers.RSC ADVANCES,5(69),55619-55624. |
| MLA | Qing, Wanmei,et al."Modulating carrier transfer ability-linker effect on thieno[3,4-c]pyrrole-4,6-dione based conjugated polymers".RSC ADVANCES 5.69(2015):55619-55624. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。