Synthesis of Graphdiyne Nanowalls Using Acetylenic Coupling Reaction
文献类型：期刊论文
| 作者 | Zhou, Jingyuan1,2; Gao, Xin1; Liu, Rong1,2; Xie, Ziqian1; Yang, Jin2,3,4; Zhang, Shuqing1,2; Zhang, Gengmin3,4; Liu, Huibiao5; Li, Yuliang5; Zhang, Jin1 |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2015-06-24 |
| 卷号 | 137期号:24页码:7596-7599 |
| 英文摘要 | Synthesizing graphdiyne with a-well-defined structure is a great challenge. We reported herein a rational approach to synthesize graphdiyne nanowalls using,a modified Glaser-Hay coupling reaction. Hexaethynylbenzene and copper plate were selected as monomer and substrate, respectively. By adjusting, the ratio of added organic alkali along with the amount of Monomer, the proper amount of copper ions was dissolved into the solution, this forming catalytic reaction sites. With a rapid reaction rate of Glaser-Hay coupling, graphdiyne grew vertically at these sites first, and then with more copper ions dissolved, uniform graphdiyne nanowalls formed on the surface of copper substrate: Raman spectra, UV-vis spectra, and HRTEM results' confirmed the features of graphdiyne. These graphdiyne nanowalls also exhibited excellent and stable field-emission properties. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/27910]  |
| 专题 | 化学研究所_有机固体实验室 |
| 作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, Beijing Sci & Engn Ctr Nanocarbons, Ctr Nanochem,Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China 2.Peking Univ, Acad Adv Interdisciplinary Studies, Beijing 100871, Peoples R China 3.Peking Univ, Key Lab Phys & Chem Nanodevices, Beijing 100871, Peoples R China 4.Peking Univ, Dept Elect, Beijing 100871, Peoples R China 5.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Jingyuan,Gao, Xin,Liu, Rong,et al. Synthesis of Graphdiyne Nanowalls Using Acetylenic Coupling Reaction[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2015,137(24):7596-7599. |
| APA | Zhou, Jingyuan.,Gao, Xin.,Liu, Rong.,Xie, Ziqian.,Yang, Jin.,...&Liu, Zhongfan.(2015).Synthesis of Graphdiyne Nanowalls Using Acetylenic Coupling Reaction.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,137(24),7596-7599. |
| MLA | Zhou, Jingyuan,et al."Synthesis of Graphdiyne Nanowalls Using Acetylenic Coupling Reaction".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 137.24(2015):7596-7599. |
入库方式： OAI收割
来源：化学研究所
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