A two-dimensional pi-d conjugated coordination polymer with extremely high electrical conductivity and ambipolar transport behaviour
文献类型：期刊论文
| 作者 | Huang, Xing1; Sheng, Peng1; Tu, Zeyi1; Zhang, Fengjiao1; Wang, Junhua2; Geng, Hua1; Zou, Ye1; Di, Chong-an1; Yi, Yuanping1; Sun, Yimeng1 |
| 刊名 | NATURE COMMUNICATIONS
 |
| 出版日期 | 2015-06-01 |
| 卷号 | 6 |
| 英文摘要 | Currently, studies on organic two-dimensional (2D) materials with special optic-electronic properties are attracting great research interest. However, 2D organic systems possessing promising electrical transport properties are still rare. Here a highly crystalline thin film of a copper coordination polymer, Cu-BHT (BHT = benzenehexathiol), is prepared via a liquid-liquid interface reaction between BHT/dichloromethane and copper(II) nitrate/H2O. The morphology and structure characterization reveal that this film is piled up by nanosheets of 2D lattice of [Cu-3(C6S6)](n), which is further verified by quantum simulation. Four-probe measurements show that the room temperature conductivity of this material can reach up to 1,580 S cm (-1), which is the highest value ever reported for coordination polymers. Meanwhile, it displays ambipolar charge transport behaviour and extremely high electron and hole mobilities (99 cm(2) V (-1) s (-1) for holes and 116 cm(2) V (-1) s (-1) for electrons) under field-effect modulation. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/27921]  |
| 专题 | 化学研究所_有机固体实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Organ Solids, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Phys, Daniel Chee Tsui Lab, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Xing,Sheng, Peng,Tu, Zeyi,et al. A two-dimensional pi-d conjugated coordination polymer with extremely high electrical conductivity and ambipolar transport behaviour[J]. NATURE COMMUNICATIONS,2015,6. |
| APA | Huang, Xing.,Sheng, Peng.,Tu, Zeyi.,Zhang, Fengjiao.,Wang, Junhua.,...&Zhu, Daoben.(2015).A two-dimensional pi-d conjugated coordination polymer with extremely high electrical conductivity and ambipolar transport behaviour.NATURE COMMUNICATIONS,6. |
| MLA | Huang, Xing,et al."A two-dimensional pi-d conjugated coordination polymer with extremely high electrical conductivity and ambipolar transport behaviour".NATURE COMMUNICATIONS 6(2015). |
入库方式： OAI收割
来源：化学研究所
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