Pyridine-bridged diketopyrrolopyrrole conjugated polymers for field-effect transistors and polymer solar cells
文献类型：期刊论文
| 作者 | Zhang, Xiaotao1; Xiao, Chengyi1; Zhang, Andong1; Yang, Fangxu1; Dong, Huanli1; Wang, Zhaohui1; Zhan, Xiaowei2; Li, Weiwei1; Hu, Wenping1,3,4 |
| 刊名 | POLYMER CHEMISTRY
 |
| 出版日期 | 2015 |
| 卷号 | 6期号:26页码:4775-4783 |
| 英文摘要 | Five wide or medium band gap diketopyrrolopyrrole (DPP)-based conjugated polymers with pyridine as bridges were developed for organic field-effect transistors (OFETs) and polymer solar cells (PSCs). By introducing copolymerized aromatic building blocks from strong electron-donating units to electron-deficient units into the conjugated backbone, the highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) levels of the DPP polymers were tailored to the low-lying position. Therefore, the polarity of charge transport in OFETs can be switched from p-type to n-type. The DPP polymer with a low-lying LUMO of -3.80 eV provides a hole-only mobility of 2.95 x 10(-2) cm(2) V-1 s(-1), while an electron-only mobility of 1.24 x 10(-3) cm(2) V-1 s(-1) is found in the DPP polymer with a LUMO of -4.22 eV. Further investigation of photovoltaic cells based on these DPP polymers shows a modest power conversion efficiency (PCE) of around 2%. Our results demonstrate that wide band gap pyridine-bridged DPP polymers have potential application in OFETs and OSCs by adjusting their energy level with alternated units on the conjugated backbone. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/27977]  |
| 专题 | 化学研究所_有机固体实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Peking Univ, Coll Engn, Dept Mat Sci & Engn, Beijing 100871, Peoples R China 3.Tianjin Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300072, Peoples R China 4.Tianjin Univ, Dept Chem, Tianjin 300072, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Xiaotao,Xiao, Chengyi,Zhang, Andong,et al. Pyridine-bridged diketopyrrolopyrrole conjugated polymers for field-effect transistors and polymer solar cells[J]. POLYMER CHEMISTRY,2015,6(26):4775-4783. |
| APA | Zhang, Xiaotao.,Xiao, Chengyi.,Zhang, Andong.,Yang, Fangxu.,Dong, Huanli.,...&Hu, Wenping.(2015).Pyridine-bridged diketopyrrolopyrrole conjugated polymers for field-effect transistors and polymer solar cells.POLYMER CHEMISTRY,6(26),4775-4783. |
| MLA | Zhang, Xiaotao,et al."Pyridine-bridged diketopyrrolopyrrole conjugated polymers for field-effect transistors and polymer solar cells".POLYMER CHEMISTRY 6.26(2015):4775-4783. |
入库方式： OAI收割
来源：化学研究所
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