Synthesis of a naphthalenediimide-based cyclophane for controlling anion-arene interactions
文献类型：期刊论文
| 作者 | Li, Yongjun1; Zhao, Yingjie1,2; Jiang, Runsheng1,2; Liu, Huibiao1; Li, Yuliang1 |
| 刊名 | INORGANIC CHEMISTRY FRONTIERS
 |
| 出版日期 | 2014 |
| 卷号 | 1期号:9页码:661-667 |
| 英文摘要 | A cationic cyclophane based on a photoactive naphthalenediimide (NDI) moiety and cationic triazolium units has been prepared. This system was employed to control the interactions between anions and the NDI motif and tune the charge transfer properties of the NDI with different anions. High selectivity was observed for fluoride anions, which preferred to interact with the NDI through a SOMO-LUMO-based electronic transition to form NDI radical anions in solution. This cyclophane can crystallize to form a porous lattice which allowed for a gradual leaking of PF6- anions, with replacement by smaller-sized halides. Charge transfer complexes were formed upon replacing the non-nucleophilic hexafluorophosphate anions with halides in the molecular crystals. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/29231]  |
| 专题 | 化学研究所_有机固体实验室 |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Organ Solids, Inst Chem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Yongjun,Zhao, Yingjie,Jiang, Runsheng,et al. Synthesis of a naphthalenediimide-based cyclophane for controlling anion-arene interactions[J]. INORGANIC CHEMISTRY FRONTIERS,2014,1(9):661-667. |
| APA | Li, Yongjun,Zhao, Yingjie,Jiang, Runsheng,Liu, Huibiao,&Li, Yuliang.(2014).Synthesis of a naphthalenediimide-based cyclophane for controlling anion-arene interactions.INORGANIC CHEMISTRY FRONTIERS,1(9),661-667. |
| MLA | Li, Yongjun,et al."Synthesis of a naphthalenediimide-based cyclophane for controlling anion-arene interactions".INORGANIC CHEMISTRY FRONTIERS 1.9(2014):661-667. |
入库方式： OAI收割
来源：化学研究所
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