Spirobifluorene-based acceptors for polymer solar cells: Effect of isomers
文献类型：期刊论文
| 作者 | Wang, Jiayu1; Dai, Shuixing1; Yao, Yuehan1; Cheng, Pei3,4; Lin, Yuze2,3,4; Zhan, Xiaowei1 |
| 刊名 | DYES AND PIGMENTS
 |
| 出版日期 | 2015-12-01 |
| 卷号 | 123页码:16-25 |
| 关键词 | Isomer Non-fullerene acceptor Spirobifluorene Polymer solar cell Solution process Fullerene free |
| 英文摘要 | Two spirobifluorene-based isomeric acceptors (SBF1 and SBF2) with electron-withdrawing 1,1-dicyanomethylene-3-indanone as end groups were theoretically studied, synthesized and applied as electron acceptors for solution-processed polymer solar cells (PSCs). SBF1 possessed three-dimensional molecular structure while SBF2 was more planar. The effect of molecular configuration on absorption, energy level, charge transport, morphology and PSC performance was investigated. These molecules exhibited good thermal stability with decomposition temperatures of 345-348 degrees C, broad absorption in visible region (400-650 nm), and proper HOMO (-5.96 to -5.94 eV) and LUMO (-3.86 to -3.78 eV) energy levels. The mobility of SBF2 (7.2 x 10(-4) cm(2) V-1 s(-1)) was one order of magnitude higher than that of SBF1 (6.1 x 10(-5) cm(2) V-1 s(-1)). When blending with low-bandgap polymer donor PBDITT-C-T, the power conversion efficiencies of SBF2-based PSCs were ca. 50% higher than those of SBF1-based devices. (C) 2015 Elsevier Ltd. All rights reserved. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/29757]  |
| 专题 | 化学研究所_有机固体实验室 |
| 作者单位 | 1.Peking Univ, Dept Mat Sci & Engn, Coll Engn, Key Lab Polymer Chem & Phys,Minist Educ, Beijing 100871, Peoples R China 2.Capital Normal Univ, Dept Chem, Beijing 100048, Peoples R China 3.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China 4.Chinese Acad Sci, Key Lab Organ Solids, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Jiayu,Dai, Shuixing,Yao, Yuehan,et al. Spirobifluorene-based acceptors for polymer solar cells: Effect of isomers[J]. DYES AND PIGMENTS,2015,123:16-25. |
| APA | Wang, Jiayu,Dai, Shuixing,Yao, Yuehan,Cheng, Pei,Lin, Yuze,&Zhan, Xiaowei.(2015).Spirobifluorene-based acceptors for polymer solar cells: Effect of isomers.DYES AND PIGMENTS,123,16-25. |
| MLA | Wang, Jiayu,et al."Spirobifluorene-based acceptors for polymer solar cells: Effect of isomers".DYES AND PIGMENTS 123(2015):16-25. |
入库方式： OAI收割
来源：化学研究所
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