Synthetic Study toward the Misassigned (+/-)-Tronoharine
文献类型:期刊论文
作者 | Zhong,Xue; Li,You; Zhang,Jing; Han,Fu-She |
刊名 | organic letters
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出版日期 | 2015 |
卷号 | 17期号:3页码:720-723 |
关键词 | ACID (+/-)-MERSICARPINE TRONOHARINE CYCLIZATION ALKALOIDS KETONES CONCISE |
通讯作者 | han,fs |
英文摘要 | the synthesis of a pentacyclic indole compound corresponding to the core structure of the misassigned indole alkaloid, tronoharine (1), is presented. the key reactions were a formal [3 + 3] cycloaddition of an indol-2-yl carbinol with an azadiene for the construction of the 6/5/6/6 tetracyclic system containing an all-carbon quaternary center and an intramolecular substitution reaction of an amine and a triflate for the creation of the bridged azepine ring. in addition, some other interesting transformations discovered during the synthetic studies are also discussed. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2016-05-09 |
源URL | [http://ir.ciac.jl.cn/handle/322003/64771] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Zhong,Xue,Li,You,Zhang,Jing,et al. Synthetic Study toward the Misassigned (+/-)-Tronoharine[J]. organic letters,2015,17(3):720-723. |
APA | Zhong,Xue,Li,You,Zhang,Jing,&Han,Fu-She.(2015).Synthetic Study toward the Misassigned (+/-)-Tronoharine.organic letters,17(3),720-723. |
MLA | Zhong,Xue,et al."Synthetic Study toward the Misassigned (+/-)-Tronoharine".organic letters 17.3(2015):720-723. |
入库方式: OAI收割
来源:长春应用化学研究所
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