Dual-doped carbon composite for efficient oxygen reduction via electrospinning and incipient impregnation
文献类型：期刊论文
| 作者 | Yang,Wenxiu; Zhang,Yingqiu; Liu,Changyu; Jia,Jianbo |
| 刊名 | journal of power sources
 |
| 出版日期 | 2015 |
| 卷号 | 274页码:595-603 |
| 关键词 | METAL-FREE ELECTROCATALYSTS FUEL-CELLS ALKALINE MEDIA GRAPHENE OXIDE NITROGEN CATALYST NANOTUBES SULFUR IRON PERFORMANCE |
| 通讯作者 | jia,jb |
| 英文摘要 | this paper describes the preparation, characterization, and electrochemical properties of a porous dual-doped carbon composite. the composite is prepared by electrospinning of polyacrylonitrile solution with graphene oxide, and then incipient impregnating with fe(no3)(3) solution followed by calcination in n-2 atmosphere. the structure and composition of the composite are characterized by scanning electron microscopy, nitrogen adsorption isotherms, x-ray photoelectron spectroscopy, surface-enhanced raman scattering, and x-ray diffraction, respectively. under the optimal conditions, the resultant composite modified electrode exhibits excellent tolerance of methanol crossover, high current density (5.30 and 6.04 ma cm(-2) in alkaline and acidic solutions) and good durability (similar to 92.3% and 79.4% after 10,000 s in alkaline and acidic solutions, respectively) toward oxygen reduction reaction (orr). remarkably, the modified electrode displays a four-electron transfer process for orr. these above excellent electrocatalytic activity of the composite should be attributed to the synergistic effect of planar-n (pyridinic and pyrrolic n), fe-containing nanoparticles and reduced graphene oxide. (c) 2014 elsevier b.v. all rights reserved. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/64776]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Yang,Wenxiu,Zhang,Yingqiu,Liu,Changyu,et al. Dual-doped carbon composite for efficient oxygen reduction via electrospinning and incipient impregnation[J]. journal of power sources,2015,274:595-603. |
| APA | Yang,Wenxiu,Zhang,Yingqiu,Liu,Changyu,&Jia,Jianbo.(2015).Dual-doped carbon composite for efficient oxygen reduction via electrospinning and incipient impregnation.journal of power sources,274,595-603. |
| MLA | Yang,Wenxiu,et al."Dual-doped carbon composite for efficient oxygen reduction via electrospinning and incipient impregnation".journal of power sources 274(2015):595-603. |
入库方式： OAI收割
来源：长春应用化学研究所
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