中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Porous carbon nanotubes decorated with nanosized cobalt ferrite as anode materials for high-performance lithium-ion batteries

文献类型:期刊论文

作者Wang,Lingyan; Zhuo,Linhai; Cheng,Haiyang; Zhang,Chao; Zhao,Fengyu
刊名journal of power sources
出版日期2015
卷号283页码:289-299
关键词ELECTROCHEMICAL PERFORMANCE FE3O4 NANOPARTICLES RATE CAPABILITY REVERSIBLE CAPACITY FACILE SYNTHESIS GRAPHENE STORAGE ELECTRODES COFE2O4 ARCHITECTURES
通讯作者zhao,fy
英文摘要generally, the fast ion/electron transport and structural stability dominate the superiority in lithium-storage applications. in this work, porous carbon nanotubes decorated with nanosized cofe2o4 particles (p-cnts@cfo) have been rationally designed and synthesized by the assistance of supercritical carbon dioxide (scco(2)). when tested as anode materials for lithium-ion batteries, the p-cnts@cfo composite exhibits outstanding electrochemical behavior with high lithium-storage capacity (1077 mah g(-1) after 100 cycles) and rate capability (694 mah g(-1) at 3 a g(-1)). these outstanding electrochemical performances are attributed to the synergistic effect of porous p-cnts and nanosized cfo. compared to pristine cnts, the p-cnts with substantial pores in the tubes possess largely increased specific surface area and rich oxygen-containing functional groups. the porous structure can not only accommodate the volume change during lithiation/delithiation processes, but also provide bicontinuous electron/ion pathways and large electrode/electrolyte interface, which facilitate the ion diffusion kinetics, improving the rate performance. moreover, the cfo particles are bonded strongly to the p-cnts through metal-oxygen bridges, which facilitate the electron fast capture from p-cnts to cfo, and thus resulting in a high reversible capacity and excellent rate performance. overall, the porous p-cnts provide an efficient way for ion diffusion and continuous electron transport as anode materials. (c) 2015 elsevier b.v. all rights reserved.
收录类别SCI
语种英语
公开日期2016-05-09
源URL[http://ir.ciac.jl.cn/handle/322003/64785]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Wang,Lingyan,Zhuo,Linhai,Cheng,Haiyang,et al. Porous carbon nanotubes decorated with nanosized cobalt ferrite as anode materials for high-performance lithium-ion batteries[J]. journal of power sources,2015,283:289-299.
APA Wang,Lingyan,Zhuo,Linhai,Cheng,Haiyang,Zhang,Chao,&Zhao,Fengyu.(2015).Porous carbon nanotubes decorated with nanosized cobalt ferrite as anode materials for high-performance lithium-ion batteries.journal of power sources,283,289-299.
MLA Wang,Lingyan,et al."Porous carbon nanotubes decorated with nanosized cobalt ferrite as anode materials for high-performance lithium-ion batteries".journal of power sources 283(2015):289-299.

入库方式: OAI收割

来源:长春应用化学研究所

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