Entropy-Driven Hierarchical Nanostructures from Cooperative Self-Assembly of Gold Nanoparticles/Block Copolymers under Three-Dimensional Confinement
文献类型：期刊论文
| 作者 | Yan,Nan; Liu,Hongxia; Zhu,Yutian; Jiang,Wei; Dong,Zeyuan |
| 刊名 | macromolecules
 |
| 出版日期 | 2015 |
| 卷号 | 48期号:16页码:5980-5987 |
| 关键词 | MICROPHASE-SEPARATED STRUCTURES BLOCK-COPOLYMERS TRIBLOCK COPOLYMERS DIBLOCK COPOLYMERS THIN-FILMS INTERFACIAL INSTABILITIES POLYMER PARTICLES FRUSTRATED PHASES 3D CONFINEMENT MICELLES |
| 通讯作者 | zhu,yt |
| 英文摘要 | the cooperative self-assembly of polystyrene-b-poly(4-vinylpyridine) block copolymers (bcps) and gold nanopartides (aunps) confined within the emulsion droplets is studied by combining both the experiments and monte carlo simulations. the results indicate that the entropic interaction between the aunps and bcp domain is a critical parameter to dominate the spatial arrangement of aunps and the nanostructure of the hybrid nanopartides, which can be utilized to design novel hierarchical hybrid nanopartides. based on this theoretical observation, a large number of unique janus hybrid nanopartides, including pupa-like nanopartides with aunps concentrated at one pole of the particles, spherical nanoparticles with aunps enriched in a bulge on the sphere surface, and the gourd-like, clover-like, and four-leaf-clover-like nanoparticles from the further hierarchical assembly of small hybrid janus nanopartides, are fabricated via three-dimensional (3d) confined self-assembly. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000360324400060 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/64812]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Yan,Nan,Liu,Hongxia,Zhu,Yutian,et al. Entropy-Driven Hierarchical Nanostructures from Cooperative Self-Assembly of Gold Nanoparticles/Block Copolymers under Three-Dimensional Confinement[J]. macromolecules,2015,48(16):5980-5987. |
| APA | Yan,Nan,Liu,Hongxia,Zhu,Yutian,Jiang,Wei,&Dong,Zeyuan.(2015).Entropy-Driven Hierarchical Nanostructures from Cooperative Self-Assembly of Gold Nanoparticles/Block Copolymers under Three-Dimensional Confinement.macromolecules,48(16),5980-5987. |
| MLA | Yan,Nan,et al."Entropy-Driven Hierarchical Nanostructures from Cooperative Self-Assembly of Gold Nanoparticles/Block Copolymers under Three-Dimensional Confinement".macromolecules 48.16(2015):5980-5987. |
入库方式： OAI收割
来源：长春应用化学研究所
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