中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
One-pot approach to prepare high-performance graphene-reinforced poly(vinyl chloride) using lithium alkyl as covalent bonding agent

文献类型:期刊论文

作者Yao,Kun; Zhang,Guangchun; Lin,Yichao; Gong,Jiang; Na,Hui; Tang,Tao
刊名polymer chemistry
出版日期2015
卷号6期号:3页码:389-396
关键词WALLED CARBON NANOTUBES POLYMER NANOCOMPOSITES ELECTRICAL-CONDUCTIVITY FUNCTIONALIZED GRAPHENE MECHANICAL-PROPERTIES COMPOSITES FLAMMABILITY REOXIDATION TOUGHNESS NETWORKS
通讯作者tang,t
英文摘要a novel one-pot approach has been demonstrated for the preparation of poly(vinyl chloride) (pvc)/graphene nanocomposites based on the grafting reaction of pvc chains to graphene using n-buli as an initiator. the grafting reaction was successfully confirmed by ft-ir, xps, tga, tem and icp-oes. raman measurements showed that the structural integrity of graphene framework was retained after surface functionalization, leading to the development of homogeneous nanocomposites with well-dispersed graphene in pvc matrix. because of a strengthened interfacial interaction and improved dispersion of graphene in the resultant pvc/graphene nanocomposites, the graphene platelets could change their random alignment into oriented alignment parallel to the stretching direction with the movement of the matrix during deformation. as expected, the pvc matrix filled with very low loading of graphene showed significantly improved mechanical properties and electrical conductivity over their counterparts without n-buli treatment. the results show that it is very important to rationally and simultaneously control dispersion state, structural integrity of graphene and interfacial interaction between graphene and polymer matrix to fabricate high-performance polymer nanocomposites.
收录类别SCI
语种英语
公开日期2016-05-09
源URL[http://ir.ciac.jl.cn/handle/322003/64852]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Yao,Kun,Zhang,Guangchun,Lin,Yichao,et al. One-pot approach to prepare high-performance graphene-reinforced poly(vinyl chloride) using lithium alkyl as covalent bonding agent[J]. polymer chemistry,2015,6(3):389-396.
APA Yao,Kun,Zhang,Guangchun,Lin,Yichao,Gong,Jiang,Na,Hui,&Tang,Tao.(2015).One-pot approach to prepare high-performance graphene-reinforced poly(vinyl chloride) using lithium alkyl as covalent bonding agent.polymer chemistry,6(3),389-396.
MLA Yao,Kun,et al."One-pot approach to prepare high-performance graphene-reinforced poly(vinyl chloride) using lithium alkyl as covalent bonding agent".polymer chemistry 6.3(2015):389-396.

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来源:长春应用化学研究所

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