Superior catalytic performance of Ce1-xBixO2-delta solid solution and Au/Ce1-xBixO2-delta for 5-hydroxymethylfurfural conversion in alkaline aqueous solution
文献类型：期刊论文
| 作者 | Miao,Zhenzhen; Zhang,Yibo; Pan,Xiqiang; Wu,Tianxiao; Zhang,Bin; Li,Jingwei; Yi,Ting; Zhang,Zhendong; Yang,Xiangguang |
| 刊名 | catalysis science & technology
 |
| 出版日期 | 2015 |
| 卷号 | 5期号:2页码:1314-1322 |
| 关键词 | SELECTIVE OXIDATION 2 GOLD NANOPARTICLES AEROBIC OXIDATION CERIA NANORODS BENZYL ALCOHOL SUPPORTED GOLD CO OXIDATION LIQUID-PHASE BIOMASS 5-FURANDICARBOXYLIC ACID |
| 通讯作者 | miao,zz |
| 英文摘要 | porous bi-doped ceria(ce1-xbixo2-delta solid solution) was prepared by the easy citrate method and then used as a supporting material for au nanoparticles (nps) obtained by deposition-precipitation. in the presence of o-2, ce1-xbixo2-delta (0.08 <= x <= 0.5) efficiently catalyzed the conversion of 5-hydroxymethylfurfural (hmf) to 5-hydroxymethyl-2-furancarboxylic acid (hfca) and 2,5-bishydroxymethylfuran (bhmf) in alkaline aqueous solution without degradation of hmf. the excellent catalytic activity was attributed to the oxygen activation and hydride transfer enhanced by bi doping and the large amount of oxygen vacancies. after au nps were supported on ce1-xbixo2-delta (x <= 0.2), the presence of au delta+ facilitated the activation of the c-h bond in the hydroxymethyl group and then the production of 2,5-furandicarboxylic acid (fdca) as an end product, inhibiting the generation of bhmf. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/64868]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Miao,Zhenzhen,Zhang,Yibo,Pan,Xiqiang,et al. Superior catalytic performance of Ce1-xBixO2-delta solid solution and Au/Ce1-xBixO2-delta for 5-hydroxymethylfurfural conversion in alkaline aqueous solution[J]. catalysis science & technology,2015,5(2):1314-1322. |
| APA | Miao,Zhenzhen.,Zhang,Yibo.,Pan,Xiqiang.,Wu,Tianxiao.,Zhang,Bin.,...&Yang,Xiangguang.(2015).Superior catalytic performance of Ce1-xBixO2-delta solid solution and Au/Ce1-xBixO2-delta for 5-hydroxymethylfurfural conversion in alkaline aqueous solution.catalysis science & technology,5(2),1314-1322. |
| MLA | Miao,Zhenzhen,et al."Superior catalytic performance of Ce1-xBixO2-delta solid solution and Au/Ce1-xBixO2-delta for 5-hydroxymethylfurfural conversion in alkaline aqueous solution".catalysis science & technology 5.2(2015):1314-1322. |
入库方式： OAI收割
来源：长春应用化学研究所
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