Inherently chiral biscalixarene cone-cone conformers consisting of calix[4]arene and calix[5]arene subunits
文献类型：期刊论文
| 作者 | Li, Si-Zhe1; Yang, Ke1; Liu, Hong-Bing3; Xia, Yu-Xiang1; Zhu, Rong-Xiu2; Luo, Jun1; Wan, Qian1 |
| 刊名 | TETRAHEDRON LETTERS
 |
| 出版日期 | 2013-10-30 |
| 卷号 | 54期号:44页码:5901-5906 |
| 关键词 | Inherently chiral Biscalixarene Calixarene Optical resolution |
| 英文摘要 | Inherently chiral biscalixarenes with hetero-cavities were synthesized by a covalent assembly of p-tertbutylcalix[5]arene with a 1,3-substituted calix[4]arene via 1,3-alkylation reaction and subsequent desymmetrization. The racemates were resolved by chiral HPLC method. H-1 NMR spectra, VT-NMR spectra, and theoretical calculations support that the calix[5]arene subunit of the inherently chiral calix[4][5]arene ester adopts a cone-in conformation, with the aromatic ring bearing the CH2CO2Et group tilting inward the calix[5]arene cavity. By contrast, such a cone-in structural feature of the calix[5]arene subunit disappears for the corresponding inherently chiral calix[4][5]arene carboxylic acid, due to the intramolecular hydrogen bonding between the carboxyl group and an ethereal oxygen of the glycolic chain. (C) 2013 Elsevier Ltd. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Organic |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | ABSOLUTE-CONFIGURATION ; RESOLUTION ; FUNCTIONALIZATION ; RECOGNITION ; CALIXARENES ; DERIVATIVES ; BINDING |
| 收录类别 | SCI ; IC |
| 语种 | 英语 |
| WOS记录号 | WOS:000325666500018 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/857]  |
| 专题 | 武汉物理与数学研究所_原子分子光物理研究部 |
| 作者单位 | 1.Huazhong Univ Sci & Technol, Tongji Sch Pharm, Wuhan 430030, Peoples R China 2.Shandong Univ, Inst Theoret Chem, Sch Chem & Chem Engn, Jinan 250100, Peoples R China 3.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan Ctr Magnet Resonance, Wuhan 430071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Si-Zhe,Yang, Ke,Liu, Hong-Bing,et al. Inherently chiral biscalixarene cone-cone conformers consisting of calix[4]arene and calix[5]arene subunits[J]. TETRAHEDRON LETTERS,2013,54(44):5901-5906. |
| APA | Li, Si-Zhe.,Yang, Ke.,Liu, Hong-Bing.,Xia, Yu-Xiang.,Zhu, Rong-Xiu.,...&Wan, Qian.(2013).Inherently chiral biscalixarene cone-cone conformers consisting of calix[4]arene and calix[5]arene subunits.TETRAHEDRON LETTERS,54(44),5901-5906. |
| MLA | Li, Si-Zhe,et al."Inherently chiral biscalixarene cone-cone conformers consisting of calix[4]arene and calix[5]arene subunits".TETRAHEDRON LETTERS 54.44(2013):5901-5906. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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