Rotamers of 3,4-difluoroanisole studied by two-color resonant two-photon mass-analyzed threshold ionization spectroscopy
文献类型：期刊论文
| 作者 | Xu, Yanqi1,3; Tzeng, Sheng Yuan1,2; Zhang, Bing3; Tzeng, Wen Bih1,2 |
| 刊名 | SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
 |
| 出版日期 | 2013-02-01 |
| 卷号 | 102页码:365-370 |
| 关键词 | Cation spectroscopy Threshold ionization Resonant ionization Rotamers 3 4-Difluoroanisole |
| 英文摘要 | We reported the vibronic and cation spectra of 3,4-difluoroanisole. The band origins of the S-1-S-0 electronic transition of the cis and trans rotamers appear at 35,505 +/- 2 and 35,711 +/- 2 cm(-1) and the adiabatic ionization energies are determined to be 67,780 +/- 5 and 68,125 +/- 5 cm(-1), respectively. Most of the observed active vibrations in the electronically excited S-1 and cationic ground D-0 states mainly involve in-plane ring deformation and substituent-sensitive bending vibrations. Analysis of the obtained vibronic and cation spectra suggests that the molecular geometry, symmetry, and vibrational coordinates of the cation in the D-0 state are like those of the neutral species in the S-1 state for these two isomeric species. (C) 2012 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Spectroscopy |
| 研究领域[WOS] | Spectroscopy |
| 关键词[WOS] | QUANTUM-CHEMICAL CALCULATIONS ; HOLE-BURNING SPECTROSCOPY ; ROTATIONAL ISOMERS ; INFRARED-SPECTROSCOPY ; ELECTRON-DIFFRACTION ; CATION SPECTROSCOPY ; MICROWAVE-SPECTRUM ; P-FLUOROANILINE ; ZEKE ; METHOXYPHENOL |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000314740700047 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/965]  |
| 专题 | 武汉物理与数学研究所_原子分子光物理研究部 |
| 作者单位 | 1.Acad Sinica, Inst Atom & Mol Sci, Taipei 10617, Taiwan 2.Natl Taiwan Normal Univ, Dept Chem, Taipei 11677, Taiwan 3.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Yanqi,Tzeng, Sheng Yuan,Zhang, Bing,et al. Rotamers of 3,4-difluoroanisole studied by two-color resonant two-photon mass-analyzed threshold ionization spectroscopy[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2013,102:365-370. |
| APA | Xu, Yanqi,Tzeng, Sheng Yuan,Zhang, Bing,&Tzeng, Wen Bih.(2013).Rotamers of 3,4-difluoroanisole studied by two-color resonant two-photon mass-analyzed threshold ionization spectroscopy.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,102,365-370. |
| MLA | Xu, Yanqi,et al."Rotamers of 3,4-difluoroanisole studied by two-color resonant two-photon mass-analyzed threshold ionization spectroscopy".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 102(2013):365-370. |
入库方式： OAI收割
来源：武汉物理与数学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。