The REMPI spectra of o-, m- and p-bromofluorobenzene and the photodissociation of p-bromofluorobenzene
文献类型：期刊论文
| 作者 | Qin, Chen1,3; Wang, Jian1; Zhu, Rong-Shu2; Zhang, Bing1 |
| 刊名 | JOURNAL OF MOLECULAR SPECTROSCOPY
 |
| 出版日期 | 2012-03-01 |
| 卷号 | 273页码:37-43 |
| 关键词 | Bromofluorobenzene REMPI Vibronic spectra Photodissociation Potential barrier height |
| 英文摘要 | The vibrations of o-, m- and p-bromofluorobenzene (BrFPh) in the first electronically excited state are studied by (1 + 1) resonance-enhanced two-photon ionization spectroscopy. The observed vibrational bands have been assigned on the basis of comparison with the results from theoretical calculations. The band origins of the S-1 <- S-2 electronic transitions of o-, m- and p-BrFPh, which were influenced by positive resonance effect and negative inductive effect, are found to be 36986.68 cm(-1), 36961.48 cm(-1) and 36223.20 cm(-1) respectively. Meanwhile, the potential barrier height (the energy of the crossing points between the bound SI state and a repulsive state relative to the S-1 minimum) of p-BrFPh is determined to be lower than 2815 cm(-1) (0.3490 eV) by the REMPI spectra of bromine atom and p-BrFPh molecule. (C) 2012 Elsevier Inc. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Physics, Atomic, Molecular & Chemical ; Spectroscopy |
| 研究领域[WOS] | Physics ; Spectroscopy |
| 关键词[WOS] | VIBRATIONAL-SPECTRA ; IONIZATION SPECTROSCOPY ; ISOMERS ; DIFLUOROBENZENE ; FLUOROBENZENE ; CHLOROBENZENE ; BROMOBENZENE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000303491200008 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/1671]  |
| 专题 | 武汉物理与数学研究所_原子分子光物理研究部 |
| 作者单位 | 1.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China 2.Harbin Inst Technol, Environm Sci & Engn Res Ctr, Shenzhen Grad Sch, Shenzhen 518055, Peoples R China 3.Xinjiang Normal Univ, Coll Phys & Elect Engn, Urumqi 830054, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qin, Chen,Wang, Jian,Zhu, Rong-Shu,et al. The REMPI spectra of o-, m- and p-bromofluorobenzene and the photodissociation of p-bromofluorobenzene[J]. JOURNAL OF MOLECULAR SPECTROSCOPY,2012,273:37-43. |
| APA | Qin, Chen,Wang, Jian,Zhu, Rong-Shu,&Zhang, Bing.(2012).The REMPI spectra of o-, m- and p-bromofluorobenzene and the photodissociation of p-bromofluorobenzene.JOURNAL OF MOLECULAR SPECTROSCOPY,273,37-43. |
| MLA | Qin, Chen,et al."The REMPI spectra of o-, m- and p-bromofluorobenzene and the photodissociation of p-bromofluorobenzene".JOURNAL OF MOLECULAR SPECTROSCOPY 273(2012):37-43. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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