Supramolecular effects involving the incorporation of guest substrates in imidazolium ionic liquid networks: Recent advances and future developments
文献类型：期刊论文
| 作者 | Leclercq, Loic ; Schmitzer, Andreea R. |
| 刊名 | SUPRAMOLECULAR CHEMISTRY
 |
| 出版日期 | 2009 |
| 卷号 | 21期号:42433页码:245-263 |
| 关键词 | DIELS-ALDER REACTIONS RHODIUM-CATALYZED HYDROFORMYLATION TRANSITION-METAL NANOPARTICLES SOLVATOCHROMIC PROBE BEHAVIOR IONIZATION MASS-SPECTROMETRY FRIEDEL-CRAFTS REACTIONS BAYLIS-HILLMAN REACTION 1-BUTYL-3-METHYLIMIDAZOLIUM HEXAFLUOROPHOSPHATE CARBON-DIOXIDE MOLTEN-SALTS |
| ISSN号 | 1061-0278 |
| 中文摘要 | The interest in ionic liquids (ILs) as green solvents has grown enormously in the last few years. ILs have been proved to be convenient and economical solvents due to their efficiencies, non-toxicities and recyclabilities. Logically, these new media are used in a wide range of organic reactions. Recent investigations of the physicochemical properties of imidazolium ILs suggest that they behave as polymeric supramolecules that cannot be seen as conventional solvent. Electrostatic, H-bonds and -stacking interactions occur in imidazolium ILs. When various organic compounds are mixed with imidazolium ILs, 'inclusion complexes' are formed and complex supramolecular organisation is created. In other words, ILs can be seen as a pre-organised medium that can modify the molecular reactivity (selectivity, substrate discrimination, etc.) by the formation of 'inclusion complexes' between guests (reactive species) and the 'host networks' (ILs). This mini review is intended to describe the imidazolium IL organisation (aggregation properties, formation of 'inclusion complexes', etc.) and to underline some of the effects on the organic reactivity of the inclusion of the guest substrates in imidazolium ILs. |
| 学科主题 | Chemistry |
| 收录类别 | SCI |
| 原文出处 | 10.1080/10610270802468421 |
| 公开日期 | 2016-05-06 |
| 源URL | [http://ir.xtbg.org.cn/handle/353005/9763]  |
| 专题 | 西双版纳热带植物园_文献共享 |
| 推荐引用方式 GB/T 7714 | Leclercq, Loic,Schmitzer, Andreea R.. Supramolecular effects involving the incorporation of guest substrates in imidazolium ionic liquid networks: Recent advances and future developments[J]. SUPRAMOLECULAR CHEMISTRY,2009,21(42433):245-263. |
| APA | Leclercq, Loic,&Schmitzer, Andreea R..(2009).Supramolecular effects involving the incorporation of guest substrates in imidazolium ionic liquid networks: Recent advances and future developments.SUPRAMOLECULAR CHEMISTRY,21(42433),245-263. |
| MLA | Leclercq, Loic,et al."Supramolecular effects involving the incorporation of guest substrates in imidazolium ionic liquid networks: Recent advances and future developments".SUPRAMOLECULAR CHEMISTRY 21.42433(2009):245-263. |
入库方式： OAI收割
来源：西双版纳热带植物园
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。