Inhibiting effect of tungstic compounds on glucose hydrogenation over Ru/C catalyst
文献类型：期刊论文
| 作者 | Zhang, Junying1,2; Hou, Baolin1; Wang, Xuefei3; Li, Zhenlei1,2; Wang, Aiqin1; Zhang, Tao1 |
| 刊名 | journal of energy chemistry
 |
| 出版日期 | 2015 |
| 卷号 | 24期号:1页码:9-14 |
| 关键词 | glucose hydrogenation binary catalyst system suppressing effect retro-aldol condensation ethylene glycol tungstic compounds Ru/C catalyst |
| 通讯作者 | 王爱琴 ; 张涛 |
| 英文摘要 | the effect of acid component including various conventional acids and tungstic compounds on glucose hydrogenation over a series of binary catalyst system containing ru/c catalyst was investigated. the results showed that hcl, h2so4, h3bo3, h3po4, and hno3 had negligible effect, while all the tungstic compounds imposed inhibiting effects on the hydrogenation of glucose over ru/c catalyst, and the suppressing effect followed the order of h2wo4>hpw>wo3>amt>hsiw. this order is the same as the order of ethylene glycol (eg) yields in the one-pot conversion of glucose to eg, suggesting the important role of competition between glucose hydrogenation and retro-aldol condensation in controlling the selectivity of eg. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; energy & fuels ; engineering, chemical |
| 研究领域[WOS] | chemistry ; energy & fuels ; engineering |
| 关键词[WOS] | ethylene-glycol production ; 1,2-propylene glycol ; ruthenium catalyst ; carbide catalysts ; renewable diesel ; conversion ; cellulose ; chemicals ; biomass ; acid |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000350785000002 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/143798]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Beijing Univ Chem Technol, Coll Sci, Beijing 100029, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Junying,Hou, Baolin,Wang, Xuefei,et al. Inhibiting effect of tungstic compounds on glucose hydrogenation over Ru/C catalyst[J]. journal of energy chemistry,2015,24(1):9-14. |
| APA | Zhang, Junying,Hou, Baolin,Wang, Xuefei,Li, Zhenlei,Wang, Aiqin,&Zhang, Tao.(2015).Inhibiting effect of tungstic compounds on glucose hydrogenation over Ru/C catalyst.journal of energy chemistry,24(1),9-14. |
| MLA | Zhang, Junying,et al."Inhibiting effect of tungstic compounds on glucose hydrogenation over Ru/C catalyst".journal of energy chemistry 24.1(2015):9-14. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。