Thermo-Sensitive Polymer-Grafted Carbon Nanotubes with Temperature-Controlled Phase Transfer Behavior between Water and a Hydrophobic Ionic Liquid
文献类型：期刊论文
| 作者 | Wang, Yue1,2; Leng, Wenguang1; Gao, Yanan1; Guo, Jiansheng2 |
| 刊名 | acs applied materials & interfaces
 |
| 出版日期 | 2014-03-26 |
| 卷号 | 6期号:6页码:4143-4148 |
| 关键词 | thermo-sensitive atom transfer radical polymerization carbon nanotube phase transfer ionic liquid |
| 通讯作者 | 高艳安 |
| 英文摘要 | thermo-sensitive polymer-grafted carbon nanotubes were prepared by surface-initiated atom transfer radical polymerization and carefully characterized. a reversible, temperature-induced phase transfer behavior of these organic-inorganic hybrids between water (with a decrease in temperature to 20 degrees c) and a hydrophobic ionic liquid, 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([emim]ntf2) (with an increase in temperature to 90 degrees c), was observed. mechanism analysis suggests that this reversible phase transfer between water and [emim]ntf2 is due to the relative affinity of the two solvents for the poly(ethylene oxide) units grafted on the carbon nanotubes. our results pave the way for further design of carbon nanotube-based, recyclable phase transfer vehicles as well as heterogeneous catalysts suited for a water-hydrophobic ionic liquid biphasic system. |
| WOS标题词 | science & technology ; technology |
| 学科主题 | 物理化学 |
| 类目[WOS] | nanoscience & nanotechnology ; materials science, multidisciplinary |
| 研究领域[WOS] | science & technology - other topics ; materials science |
| 关键词[WOS] | transfer radical polymerization ; block-copolymer micelles ; hybrid nanoparticles ; aqueous-solutions ; functionalization ; catalysis ; confinement ; oxidation |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000333551500049 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/143828]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Donghua Univ, Coll Text, Shanghai 201620, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Yue,Leng, Wenguang,Gao, Yanan,et al. Thermo-Sensitive Polymer-Grafted Carbon Nanotubes with Temperature-Controlled Phase Transfer Behavior between Water and a Hydrophobic Ionic Liquid[J]. acs applied materials & interfaces,2014,6(6):4143-4148. |
| APA | Wang, Yue,Leng, Wenguang,Gao, Yanan,&Guo, Jiansheng.(2014).Thermo-Sensitive Polymer-Grafted Carbon Nanotubes with Temperature-Controlled Phase Transfer Behavior between Water and a Hydrophobic Ionic Liquid.acs applied materials & interfaces,6(6),4143-4148. |
| MLA | Wang, Yue,et al."Thermo-Sensitive Polymer-Grafted Carbon Nanotubes with Temperature-Controlled Phase Transfer Behavior between Water and a Hydrophobic Ionic Liquid".acs applied materials & interfaces 6.6(2014):4143-4148. |
入库方式： OAI收割
来源：大连化学物理研究所
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