Seed-assisted synthesis of high silica ZSM-35 through interface-induced growth over MCM-49 seeds
文献类型：期刊论文
| 作者 | Wang, Linying1,2; Tian, Peng1,2; Yuan, Yangyang1,2,3; Yang, Miao1,2; Fan, Dong1,2,3; Zhou, Hui1,2; Zhu, Wenliang1,2; Xu, Shutao1,2; Liu, Zhongmin1,2 |
| 刊名 | microporous and mesoporous materials
 |
| 出版日期 | 2014-09-15 |
| 卷号 | 196期号:1页码:89-96 |
| 关键词 | High silica ZSM-35 MCM-49 seeds High yield Interface-induced Dimethyl ether carbonylation |
| 通讯作者 | 刘中民 |
| 英文摘要 | high-silica zsm-35 has been successfully synthesized by adding non-calcined mcm-49 seeds to the initial gel without the help of organic structure-directing agents (osdas). this is the first report of seed-assisted synthesis without the common composite building units (cbus) contained in the seeds and products. high solid yields of 65-85% have been achieved, which are the highest values ever reported for the seed-assisted synthesis. alkaline treatment and hyperpolarized xe-129 nmr are employed to study the zsm-35 products, and an interface-induced growth mechanism is proposed, in which zsm-35 grows over partially dissolved mcm-49 through interface connection. it is supposed that similarity in the local atomic connection between the seeds and target zeolites, even without the common cbus, would have the possibility to lead to a successful synthesis. the catalytic performance of h-zsm-35 is tested in the dimethyl ether (dme) carbonylation, which shows excellent stability and high selectivity towards methyl acetate (ma). (c) 2014 elsevier inc. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; nanoscience & nanotechnology ; materials science, multidisciplinary |
| 研究领域[WOS] | chemistry ; science & technology - other topics ; materials science |
| 关键词[WOS] | mcm-49/zsm-35 composite zeolites ; structure-directing agents ; hyperpolarized xe-129 nmr ; osda-free synthesis ; mtw-type zeolite ; crystallization process ; aluminosilicate gels ; ferrierite ; beta ; fer |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000340333400011 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/143886]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Engn Lab Methanol Olefins, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Linying,Tian, Peng,Yuan, Yangyang,et al. Seed-assisted synthesis of high silica ZSM-35 through interface-induced growth over MCM-49 seeds[J]. microporous and mesoporous materials,2014,196(1):89-96. |
| APA | Wang, Linying.,Tian, Peng.,Yuan, Yangyang.,Yang, Miao.,Fan, Dong.,...&Liu, Zhongmin.(2014).Seed-assisted synthesis of high silica ZSM-35 through interface-induced growth over MCM-49 seeds.microporous and mesoporous materials,196(1),89-96. |
| MLA | Wang, Linying,et al."Seed-assisted synthesis of high silica ZSM-35 through interface-induced growth over MCM-49 seeds".microporous and mesoporous materials 196.1(2014):89-96. |
入库方式： OAI收割
来源：大连化学物理研究所
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