CO2 methanation on Ni/Ce0.5Zr0.5O2 catalysts for the production of synthetic natural gas
文献类型：期刊论文
| 作者 | Pan, Qiushi1,2; Peng, Jiaxi1; Sun, Tianjun1; Gao, Diannan1; Wang, Sheng1; Wang, Shudong1 |
| 刊名 | fuel processing technology
 |
| 出版日期 | 2014-07-01 |
| 卷号 | 123期号:1页码:166-171 |
| 关键词 | Methanation Ce0.5Zr0.5O2 Carbon dioxide Synthetic natural gas Oxygen vacancy Surface Ce(III) |
| 通讯作者 | 王树东 |
| 英文摘要 | a series of nickel catalysts supported on ce0.5zr0.5o2 were prepared by impregnation (imp), deposition-precipitation (dp) and urea combustion (uc) methods. their performances of co2 methanation were investigated for the production of synthetic natural gas from coal. the catalysts were characterized by bet, h-2-chemisorption, xrd, raman, xps, co2-tpd and h-2-tpr techniques. the results indicated that ni/ce0.5zr0.5o2 catalysts prepared by impregnation method showed the highest activity. it can attain 73% co2 conversion at 300 degrees c with a reaction rate of 20.5 mmol co2/(gcat min) and have a ch4 selectivity of 100%. the higher activity of imp sample is due to its higher nickel surface area, oxygen vacancies, ce(iii) and basic sites than others. (c) 2014 published by elsevier b.v. |
| 学科主题 | 物理化学 |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; energy & fuels ; engineering, chemical |
| 研究领域[WOS] | chemistry ; energy & fuels ; engineering |
| 关键词[WOS] | ceo2-zro2 mixed oxides ; solid-solutions ; carbon-dioxide ; shift reaction ; particle-size ; raman-spectroscopy ; redox behavior ; ceria ; zirconia ; oxidation |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000336469100020 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/143955]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Pan, Qiushi,Peng, Jiaxi,Sun, Tianjun,et al. CO2 methanation on Ni/Ce0.5Zr0.5O2 catalysts for the production of synthetic natural gas[J]. fuel processing technology,2014,123(1):166-171. |
| APA | Pan, Qiushi,Peng, Jiaxi,Sun, Tianjun,Gao, Diannan,Wang, Sheng,&Wang, Shudong.(2014).CO2 methanation on Ni/Ce0.5Zr0.5O2 catalysts for the production of synthetic natural gas.fuel processing technology,123(1),166-171. |
| MLA | Pan, Qiushi,et al."CO2 methanation on Ni/Ce0.5Zr0.5O2 catalysts for the production of synthetic natural gas".fuel processing technology 123.1(2014):166-171. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。