Stability of manganese-oxide-modified lanthanum strontium cobaltite in the presence of chromia
文献类型:期刊论文
作者 | Ou, Ding Rong; Cheng, Mojie |
刊名 | journal of power sources
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出版日期 | 2014-12-25 |
卷号 | 272期号:1页码:513-517 |
关键词 | Solid oxide fuel cells Perovskite Chromia Stability Solid-state reactions |
通讯作者 | 区定容 |
英文摘要 | in order to restrain the decomposition and conductivity degradation of perovskite-type conductive material in the presence of chromia, manganese oxide modification of lanthanum strontium cobaltite has been studied. la0.7sr0.3coo3-delta (lsc) and mno2-modified lsc coatings are applied onto ni-cr alloy and exposed to long-term oxidation text to examine their chemical stability. in a lsc coating, chromium species migrating from the ni-cr alloy could induce the decomposition of lsc and produce srcro4 and co-cr spinel oxides. in contrast, in the mno2-modified lsc, sr is stable and the low-conductivity phase srcro4 phase is rarely seen even the coated alloy has gone through 1000 h of oxidation tests at 800 degrees c. it highlights that mno2 modification could greatly improve the stability of lsc under cr-rich conditions. the study of solid state reactions reveals that the influence of mno2 is mainly due to the reaction between mno2 and lsc, instead of the direct reaction between mno2 and chromium oxides. (c) 2014 elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; physical sciences ; technology |
学科主题 | 物理化学 |
类目[WOS] | electrochemistry ; energy & fuels |
研究领域[WOS] | electrochemistry ; energy & fuels |
关键词[WOS] | sofc cathodes ; fuel-cells ; cr ; lani0.6fe0.4o3 ; deposition ; layers |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000344208700064 |
公开日期 | 2016-05-09 |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/143993] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Div Fuel Cells & Battery, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Ou, Ding Rong,Cheng, Mojie. Stability of manganese-oxide-modified lanthanum strontium cobaltite in the presence of chromia[J]. journal of power sources,2014,272(1):513-517. |
APA | Ou, Ding Rong,&Cheng, Mojie.(2014).Stability of manganese-oxide-modified lanthanum strontium cobaltite in the presence of chromia.journal of power sources,272(1),513-517. |
MLA | Ou, Ding Rong,et al."Stability of manganese-oxide-modified lanthanum strontium cobaltite in the presence of chromia".journal of power sources 272.1(2014):513-517. |
入库方式: OAI收割
来源:大连化学物理研究所
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