Occurrence and gas/particle partitioning of short- and medium-chain chlorinated paraffins in the atmosphere of Fildes Peninsula of Antarctica
文献类型：期刊论文
| 作者 | Ma, Xindong1,2; Zhang, Haijun2; Zhou, Hongqiang5; Na, Guangshui1; Wang, Zhen1; Chen, Chen4; Chen, Jingwen3; Chen, Jiping2 |
| 刊名 | atmospheric environment
 |
| 出版日期 | 2014-06-01 |
| 卷号 | 90期号:1页码:10-15 |
| 关键词 | Chlorinated paraffins Gas/particle partitioning Antarctic Junge-Pankow model K-OA-based model |
| 通讯作者 | 陈吉平 ; chenjingwen |
| 英文摘要 | chlorinated paraffins (cps) were measured in air samples at a remote air monitoring site established in georgia king island, fildes peninsula of antarctica (great wall station, china) to study the long-range atmospheric transport of these anthropogenic pollutants to the antarctic. gas- and particle-phase cps were collected using polyurethane foam plugs (puf) and glass fiber filters (gff) respectively during summertime of 2012. the total atmospheric levels of sccps and mccps ranged from 9.6 to 20.8 pg m(-3) (average: 14.9 pg m(-3)) and 3.7-5.2 pg m(-3) (average: 4.5 pg m(-3)), respectively. c-10 and c-11 carbon chain homologues with cl-5 and cl-6 chlorine atoms predominated in sccp formula groups both in gas- and particle-phase. significant linear correlation was found between gas/particle partition coefficients (k-p) and sub-cooled liquid vapor pressures (p degrees(l) (r-2 = 0.437, p <0.01), as well as kp and octanol air partition coefficients (k-oa) (r-2 = 0.442, p < 0.01). absolute slope values of two regression models (0.31 and 0.39) were less than 0.6 indicating that the way of absorption into organic matter of aerosol played a more important role on atmospheric partitioning and transferring of cps in remote antarctic area. both the junge pankow model and the k-oa-based model tended to underestimate the sorption of lower chlorinated cps and overestimate the sorption of highly chlorinated cps. (c) 2014 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; life sciences & biomedicine ; physical sciences |
| 学科主题 | 物理化学 |
| 类目[WOS] | environmental sciences ; meteorology & atmospheric sciences |
| 研究领域[WOS] | environmental sciences & ecology ; meteorology & atmospheric sciences |
| 关键词[WOS] | polycyclic aromatic-hydrocarbons ; polybrominated diphenyl ethers ; polychlorinated-biphenyls ; n-alkanes ; arctic air ; china ; pahs ; sea ; naphthalenes ; constants |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000335634100002 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/144024]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Natl Marine Environm Monitoring Ctr, State Ocean Adm Key Lab Ecol Environm Coastal Are, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 3.Dalian Univ Technol, Sch Environm Sci & Technol, Key Lab Ind Ecol & Environm Engn MOE, Dalian 116024, Peoples R China 4.Dalian Maritime Univ, Sch Life Sci & Technol, Dalian 116023, Peoples R China 5.Univ Paris SUD XI, Ctr Orsay, Dept Chem, F-75008 Paris, France |
| 推荐引用方式 GB/T 7714 | Ma, Xindong,Zhang, Haijun,Zhou, Hongqiang,et al. Occurrence and gas/particle partitioning of short- and medium-chain chlorinated paraffins in the atmosphere of Fildes Peninsula of Antarctica[J]. atmospheric environment,2014,90(1):10-15. |
| APA | Ma, Xindong.,Zhang, Haijun.,Zhou, Hongqiang.,Na, Guangshui.,Wang, Zhen.,...&Chen, Jiping.(2014).Occurrence and gas/particle partitioning of short- and medium-chain chlorinated paraffins in the atmosphere of Fildes Peninsula of Antarctica.atmospheric environment,90(1),10-15. |
| MLA | Ma, Xindong,et al."Occurrence and gas/particle partitioning of short- and medium-chain chlorinated paraffins in the atmosphere of Fildes Peninsula of Antarctica".atmospheric environment 90.1(2014):10-15. |
入库方式： OAI收割
来源：大连化学物理研究所
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