Reaction media dominated product selectivity in the isomerization of glucose by chromium trichloride: From aqueous to non-aqueous systems
文献类型：期刊论文
| 作者 | Jia, Songyan1; Liu, Kairui1,2; Xu, Zhanwei1; Yan, Peifang1; Xu, Wenjuan1; Liu, Xiumei1; Zhang, Z. Conrad1,3 |
| 刊名 | catalysis today
 |
| 出版日期 | 2014-10-01 |
| 卷号 | 234期号:1页码:83-90 |
| 关键词 | Glucose isomerization Chromium trichloride Fructose General behavior Aqueous media Mixed solvents |
| 通讯作者 | 张宗超 |
| 英文摘要 | while chromium trichloride hydrate (crcl3 center dot 6h(2)o) effectively catalyzed the isomerization of glucose into fructose in aqueous solution, a general product selectivity behavior was observed independent of reaction variables such as reaction time, temperature, catalyst loading, halide ion, and initial glucose concentration. by studying the mixed solution of dimethylsulfoxide (dmso) and water at varied dmso/h2o ratios, it was found that deviation from the general water-phase fructose yield curve, with concomitant 5-hydroxymethylfurfral (hmf) formation, occurred when the fructose concentration in available water became sufficiently high in dmso rich solvent mix. therefore, tuning the solvent system was the most effective approach to change the product distribution from crcl3 center dot 6h(2)o catalyzed glucose conversion. the apparent activation energy of glucose conversion in the studied system was estimated to be 58.6 kj mol(-1). special attention was also given to gain some mechanistic insights by control experiments with simple model compounds and additives, c-13 nmr and uv-vis spectroscopic analyses. (c) 2014 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | ionic liquids ; d-fructose ; efficient conversion ; catalytic conversion ; dimethyl-sulfoxide ; reducing sugars ; acid catalysts ; solid acid ; dehydration ; water |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000339132900010 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/144074]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jia, Songyan,Liu, Kairui,Xu, Zhanwei,et al. Reaction media dominated product selectivity in the isomerization of glucose by chromium trichloride: From aqueous to non-aqueous systems[J]. catalysis today,2014,234(1):83-90. |
| APA | Jia, Songyan.,Liu, Kairui.,Xu, Zhanwei.,Yan, Peifang.,Xu, Wenjuan.,...&Zhang, Z. Conrad.(2014).Reaction media dominated product selectivity in the isomerization of glucose by chromium trichloride: From aqueous to non-aqueous systems.catalysis today,234(1),83-90. |
| MLA | Jia, Songyan,et al."Reaction media dominated product selectivity in the isomerization of glucose by chromium trichloride: From aqueous to non-aqueous systems".catalysis today 234.1(2014):83-90. |
入库方式： OAI收割
来源：大连化学物理研究所
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