Tunable Bronsted Acidity-Dependent Alkylation and Alkenylation of Indoles
文献类型：期刊论文
| 作者 | Wu, Kaikai1; Wu, Ping1; Wang, Liandi1; Chen, Jiping1; Sun, Chenglin1; Yu, Zhengkun1,2 |
| 刊名 | advanced synthesis & catalysis
 |
| 出版日期 | 2014-12-15 |
| 卷号 | 356期号:18页码:3871-3880 |
| 关键词 | alkenylation alkylation Bronsted acids 3-(dimethylamino)acrylonitrile indoles |
| 通讯作者 | 余正坤 |
| 英文摘要 | the bronsted acid-mediated alkylation and alkenylation of indoles were efficiently achieved by means of 3-(dimethylamino)acrylonitrile. regulating the acidity of the reaction medium with para-toluenesulfonic acid monohydrate (p-tsoh center dot h2o) and/or acetic acid (hoac) led to versatile formation of 3-alkylated and 3-alkenylated indole derivatives under mild conditions. the 3-alkylated indole products could be nearly quantitatively transformed to the corresponding separable (e)- and (z)-3-alkenylated indoles. |
| WOS标题词 | science & technology ; physical sciences |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, applied ; chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | c-h activation ; bond activation ; practical synthesis ; functionalization ; alkenes ; c2-alkenylation ; 2-alkylation ; derivatives ; olefination ; aldehydes |
| 收录类别 | SCI ; IC |
| 语种 | 英语 |
| WOS记录号 | WOS:000346071600020 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/144082]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Kaikai,Wu, Ping,Wang, Liandi,et al. Tunable Bronsted Acidity-Dependent Alkylation and Alkenylation of Indoles[J]. advanced synthesis & catalysis,2014,356(18):3871-3880. |
| APA | Wu, Kaikai,Wu, Ping,Wang, Liandi,Chen, Jiping,Sun, Chenglin,&Yu, Zhengkun.(2014).Tunable Bronsted Acidity-Dependent Alkylation and Alkenylation of Indoles.advanced synthesis & catalysis,356(18),3871-3880. |
| MLA | Wu, Kaikai,et al."Tunable Bronsted Acidity-Dependent Alkylation and Alkenylation of Indoles".advanced synthesis & catalysis 356.18(2014):3871-3880. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。