Synthesis of ZIF-8 in a deep eutectic solvent using cooling-induced crystallisation
文献类型：期刊论文
| 作者 | Wang, Yasong1,3; Xu, Yunpeng1; Ma, Huaijun1; Xu, Renshun1; Liu, Hao1,3; Li, Dawei1,3; Tian, Zhijian1,2 |
| 刊名 | microporous and mesoporous materials
 |
| 出版日期 | 2014-09-01 |
| 卷号 | 195期号:1页码:50-59 |
| 关键词 | ZIF-8 Deep eutectic solvent Metal-organic frameworks Cooling crystallisation Precipitation |
| 通讯作者 | 田志坚 |
| 英文摘要 | we report an alternative route for the synthesis of zif-8 in a choline chloride-urea deep eutectic solvent (des). zinc nitrate hexahydrate and 2-methylimidazole were dissolved in the hot des. the zif-8 sample could precipitate from the des when the solution was cooled using rapid cooling or programmed cooling. the effect of the synthetic conditions, including the cooling rate of synthesis system and the reaction temperature, on the particle size and morphology of the zif-8 sample were investigated. the product was characterised using pxrd, sem, tg, the particle size analysis and gas-sorption. when the system was chilled via rapid cooling, the product was 0.35 mu m in size, agglomerating to form irregular spheres. after programmed cooling, the product was 5-50 mu m with a rhombic dodecahedron or truncated rhombic dodecahedron morphology, depending on the cooling rate and reaction temperature. in addition, the precipitation of zif-8 in des is also discussed. zif-8 synthesised in des also displayed excellent thermal and chemical stability, as well as good gas adsorption and separation performances. (c) 2014 elsevier inc. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; nanoscience & nanotechnology ; materials science, multidisciplinary |
| 研究领域[WOS] | chemistry ; science & technology - other topics ; materials science |
| 关键词[WOS] | zeolitic imidazolate frameworks ; room-temperature synthesis ; metal-organic frameworks ; nanocrystals ; growth ; morphology ; scattering ; mechanism ; crystal ; storage |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000337770900008 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/144090]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 10049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Yasong,Xu, Yunpeng,Ma, Huaijun,et al. Synthesis of ZIF-8 in a deep eutectic solvent using cooling-induced crystallisation[J]. microporous and mesoporous materials,2014,195(1):50-59. |
| APA | Wang, Yasong.,Xu, Yunpeng.,Ma, Huaijun.,Xu, Renshun.,Liu, Hao.,...&Tian, Zhijian.(2014).Synthesis of ZIF-8 in a deep eutectic solvent using cooling-induced crystallisation.microporous and mesoporous materials,195(1),50-59. |
| MLA | Wang, Yasong,et al."Synthesis of ZIF-8 in a deep eutectic solvent using cooling-induced crystallisation".microporous and mesoporous materials 195.1(2014):50-59. |
入库方式： OAI收割
来源：大连化学物理研究所
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