Ionothermal syntheses and characterizations of cobalt-substituted extra-large pore aluminophosphate molecular sieves with -CLO topology
文献类型：期刊论文
| 作者 | Li, Dawei1,3; Xu, Yunpeng1; Wang, Yasong1,3; Liu, Hao1,3; Wang, Bingchun1; Ma, Huaijun1; Xu, Renshun1; Tian, Zhijian1,2 |
| 刊名 | microporous and mesoporous materials
 |
| 出版日期 | 2014-11-01 |
| 卷号 | 198期号:1页码:153-160 |
| 关键词 | lonothermal synthesis Cobalt-substituted aluminophosphate -CLO Extra-large pore |
| 通讯作者 | 田志坚 |
| 英文摘要 | cobalt-substituted aluminophosphate molecular sieves with -clo structure (denoted as codnl-1) have been synthesized in the ionic liquid 1-ethyl-3-methylimidazolium bromide with 1,6-hexanediamine as the cooperative structure-directing agent (co-sda). the influence of various synthesis parameters (e.g. gel compositions and crystallization time) on the synthesis of codnl-1 has been investigated in detail. the products have been characterized by powder xrd, sem, xrf, tg, n-2-adsorption, diffuse reflectance uv-vis spectroscopy, al-27 and p-31 mas nmr spectroscopy and in situ xrd. powder xrd, tg, chemical analysis and nmr indicate the incorporation of co2+ ions into the -clo framework. uv-vis spectra reveal that co2+ ions are present in tetrahedral sites of the -clo framework. in situ xrd analyses show that codnl-1 possesses good thermal stability and the cobalt content in the framework influences the thermal stability of codnl-1. (c) 2014 elsevier inc. all rights reserved. |
| 学科主题 | 物理化学 |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; nanoscience & nanotechnology ; materials science, multidisciplinary |
| 研究领域[WOS] | chemistry ; science & technology - other topics ; materials science |
| 关键词[WOS] | metal-organic frameworks ; selective oxidation ; zeolite ; catalysts ; phosphates ; magnesium ; template ; density ; alkanes ; agents |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000341899500020 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/144093]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Dawei,Xu, Yunpeng,Wang, Yasong,et al. Ionothermal syntheses and characterizations of cobalt-substituted extra-large pore aluminophosphate molecular sieves with -CLO topology[J]. microporous and mesoporous materials,2014,198(1):153-160. |
| APA | Li, Dawei.,Xu, Yunpeng.,Wang, Yasong.,Liu, Hao.,Wang, Bingchun.,...&Tian, Zhijian.(2014).Ionothermal syntheses and characterizations of cobalt-substituted extra-large pore aluminophosphate molecular sieves with -CLO topology.microporous and mesoporous materials,198(1),153-160. |
| MLA | Li, Dawei,et al."Ionothermal syntheses and characterizations of cobalt-substituted extra-large pore aluminophosphate molecular sieves with -CLO topology".microporous and mesoporous materials 198.1(2014):153-160. |
入库方式： OAI收割
来源：大连化学物理研究所
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