Ruthenium(II)-NNN complex catalyzed Oppenauer-type oxidation of secondary alcohols
文献类型：期刊论文
| 作者 | Wang, Qingfu; Du, Wangming; Liu, Tingting; Chai, Huining; Yu, Zhengkun |
| 刊名 | tetrahedron letters
 |
| 出版日期 | 2014-02-26 |
| 卷号 | 55期号:9页码:1585-1588 |
| 关键词 | Ruthenium(II) Pyridyl-imidazolyl-pyrazolyl ligand Oppenauer oxidation Secondary alcohols |
| 通讯作者 | 余正坤 |
| 英文摘要 | highly efficient oppenauer-type oxidation of secondary alcohols to the corresponding ketones has been realized by means of the ruthenium(ii) complex catalysts bearing a 2-(benzoimidazol-2-yl)-6-(3,5-dimethylpyrazol-1-yl)pyridine ligand. the oxidation reaction underwent in the presence of acetone as oxidant under mild conditions, reaching final tof values up to 3960 h(-1). the hemilability of the ligand is attributed to the high catalytic activity of these ru(ii) complexes. (c) 2014 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | asymmetric transfer hydrogenation ; heterocyclic carbene complexes ; pyrazolyl-imidazolyl ligand ; room-temperature ; ketones ; bearing ; mechanism ; peroxide ; hydride ; green |
| 收录类别 | SCI ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000332434000018 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/144204]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Qingfu,Du, Wangming,Liu, Tingting,et al. Ruthenium(II)-NNN complex catalyzed Oppenauer-type oxidation of secondary alcohols[J]. tetrahedron letters,2014,55(9):1585-1588. |
| APA | Wang, Qingfu,Du, Wangming,Liu, Tingting,Chai, Huining,&Yu, Zhengkun.(2014).Ruthenium(II)-NNN complex catalyzed Oppenauer-type oxidation of secondary alcohols.tetrahedron letters,55(9),1585-1588. |
| MLA | Wang, Qingfu,et al."Ruthenium(II)-NNN complex catalyzed Oppenauer-type oxidation of secondary alcohols".tetrahedron letters 55.9(2014):1585-1588. |
入库方式： OAI收割
来源：大连化学物理研究所
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