Biomass into chemicals: One-pot production of furan-based diols from carbohydrates via tandem reactions
文献类型：期刊论文
| 作者 | Cai, Haile1,2; Li, Changzhi1; Wang, Aiqin1; Zhang, Tao1 |
| 刊名 | catalysis today
 |
| 出版日期 | 2014-10-01 |
| 卷号 | 234期号:1页码:59-65 |
| 关键词 | 2 2 Biomass Hydrogenation Ionic liquids 5-dihydroxymethylfuran 5-dihydroxymethyltetrahydrofuran |
| 通讯作者 | 张涛 |
| 英文摘要 | in this work, the direct production of furan-based dials from carbohydrates and their upstream raw materials via one-pot tandem reactions in ionic liquid/water system is presented. in this novel reaction system, ionic liquid serves as an advantageous solvent for polysaccharide (cellulose, inulin, sucrose) hydrolysis and hexose dehydration reactions, and heterogeneous pd, pt, ir, ni, ru-based catalysts catalyze hmf hydrogenation reaction under relatively mild condition (50 degrees c, 6 mpa h-2) to afford moderate to high yield (34.0-89.3%) of furan-based diols, namely, 2,5-dihydroxymethylfuran (dhmf) and 2,5-dihydroxymethyltetrahydrofuran (dhmtf). our results show that the metal species strongly affects the selectivity of the products, while the nature of the support influences the activity of the catalysts significantly. by selecting the proper metal species and the support, controllable production of dhmf or dhmtf was realized. based on the intermediates identified and the conversion results, the proposed reaction pathway, including possible side reactions were presented. taken together, our catalytic system featured with simple process, mild condition, high yield of diols and adjustable product selectivity. the direct conversion of the carbohydrates and the upstream materials drives our technology nearer to real application for cost-efficient production of chemicals from biomass. (c) 2014 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | acid-catalyzed hydrolysis ; selective hydrogenation ; alpha,beta-unsaturated aldehydes ; renewable resources ; metal-catalysts ; ionic liquids ; cellulose ; conversion ; chemistry ; glucose |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000339132900007 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/144224]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cai, Haile,Li, Changzhi,Wang, Aiqin,et al. Biomass into chemicals: One-pot production of furan-based diols from carbohydrates via tandem reactions[J]. catalysis today,2014,234(1):59-65. |
| APA | Cai, Haile,Li, Changzhi,Wang, Aiqin,&Zhang, Tao.(2014).Biomass into chemicals: One-pot production of furan-based diols from carbohydrates via tandem reactions.catalysis today,234(1),59-65. |
| MLA | Cai, Haile,et al."Biomass into chemicals: One-pot production of furan-based diols from carbohydrates via tandem reactions".catalysis today 234.1(2014):59-65. |
入库方式： OAI收割
来源：大连化学物理研究所
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