Synthesis of Diesel or Jet Fuel Range Cycloalkanes with 2-Methylfuran and Cyclopentanone from Lignocellulose
文献类型：期刊论文
| 作者 | Li, Guangyi1,2; Li, Ning1; Wang, Xinkui3; Sheng, Xueru1,2; Li, Shanshan1,2; Wang, Aiqin1; Cong, Yu1; Wang, Xiaodong1; Zhang, Tao1 |
| 刊名 | energy & fuels
 |
| 出版日期 | 2014-08-01 |
| 卷号 | 28期号:8页码:5112-5118 |
| 通讯作者 | 李宁 ; 张涛 |
| 英文摘要 | 2-methylfuran (2-mf) and cyclopentanone (cpo) are the selective hydrogenation products of furfural, which can be produced in industrial scale with lignocellulose. in this work, renewable diesel or jet fuel range branched alkanes and cycloalkanes were first synthesized simultaneously by the solvent-free hydroxyalkylation/alkylation (haa) of 2-mf and cpo followed by hydrodeoxygenation (hdo). among the solid acid catalysts used in this work, nafion-212 resin exhibited the best activity and selectivity for the haa of 2-mf and cpo. the excellent performance of nafion-212 resin can be attributed to the high acid strength of this catalyst. after the hdo of the haa products of 2-mf and cpo over several nickel catalysts, a mixture of jet fuel range branched alkanes and cycloalkanes with relatively higher density was obtained at high carbon yield. compared with ni/sio2, acidic support loaded nickel catalysts are more active in the hdo process, which may be attributed to the promotion effect of acid sites in dehydration and the ring opening reaction of furan compounds. |
| WOS标题词 | science & technology ; technology |
| 学科主题 | 物理化学 |
| 类目[WOS] | energy & fuels ; engineering, chemical |
| 研究领域[WOS] | energy & fuels ; engineering |
| 关键词[WOS] | high-quality diesel ; tolerant solid acid ; catalytic conversion ; renewable diesel ; transportation fuels ; zirconium-phosphate ; liquid alkanes ; biomass ; hemicellulose ; cellulose |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000340808800031 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/144251]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Grad Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Dalian Univ Technol, Sch Chem Engn, Lab Adv Mat & Catalyt Engn, Dalian 116024, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Guangyi,Li, Ning,Wang, Xinkui,et al. Synthesis of Diesel or Jet Fuel Range Cycloalkanes with 2-Methylfuran and Cyclopentanone from Lignocellulose[J]. energy & fuels,2014,28(8):5112-5118. |
| APA | Li, Guangyi.,Li, Ning.,Wang, Xinkui.,Sheng, Xueru.,Li, Shanshan.,...&Zhang, Tao.(2014).Synthesis of Diesel or Jet Fuel Range Cycloalkanes with 2-Methylfuran and Cyclopentanone from Lignocellulose.energy & fuels,28(8),5112-5118. |
| MLA | Li, Guangyi,et al."Synthesis of Diesel or Jet Fuel Range Cycloalkanes with 2-Methylfuran and Cyclopentanone from Lignocellulose".energy & fuels 28.8(2014):5112-5118. |
入库方式： OAI收割
来源：大连化学物理研究所
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