Rhodium-Catalyzed Cyclization of Diynes with Nitrones: A Formal [2+2+5] Approach to Bridged Eight-Membered Heterocycles
文献类型：期刊论文
| 作者 | Wang, Chunxiang; Wang, Dongping; Yan, Hao; Wang, Haolong; Pan, Bin; Xin, Xiaoyi; Li, Xincheng; Wu, Fan; Wan, Boshun |
| 刊名 | angewandte chemie-international edition
 |
| 出版日期 | 2014-10-27 |
| 卷号 | 53期号:44页码:11940-11943 |
| 关键词 | alkenylation C H activation cyclization nitrones rhodium |
| 通讯作者 | 万伯顺 |
| 英文摘要 | n-aryl-substituted nitrones were employed as five-atom coupling partners in the rhodium-catalyzed cyclization with diynes. in this reaction, the nitrone moiety served as a directing group for the catalytic c-h activation of the n-aryl ring. this formal [2+2+5] approach allows rapid access to bridged eight-membered heterocycles with broad substrate scope. the results of this study may provide new insight into the chemistry of nitrones and find applications in the synthesis of other heterocycles. |
| 学科主题 | 物理化学 |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | diastereoselective 1,3-dipolar cycloaddition ; c-h bonds ; complexes ; palladium ; cyclopropanes ; carbene ; ketones ; 2-(1-alkynyl)-2-alken-1-ones ; pyridines ; reagents |
| 收录类别 | SCI ; IC ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000344050700042 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/144260]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Chunxiang,Wang, Dongping,Yan, Hao,et al. Rhodium-Catalyzed Cyclization of Diynes with Nitrones: A Formal [2+2+5] Approach to Bridged Eight-Membered Heterocycles[J]. angewandte chemie-international edition,2014,53(44):11940-11943. |
| APA | Wang, Chunxiang.,Wang, Dongping.,Yan, Hao.,Wang, Haolong.,Pan, Bin.,...&Wan, Boshun.(2014).Rhodium-Catalyzed Cyclization of Diynes with Nitrones: A Formal [2+2+5] Approach to Bridged Eight-Membered Heterocycles.angewandte chemie-international edition,53(44),11940-11943. |
| MLA | Wang, Chunxiang,et al."Rhodium-Catalyzed Cyclization of Diynes with Nitrones: A Formal [2+2+5] Approach to Bridged Eight-Membered Heterocycles".angewandte chemie-international edition 53.44(2014):11940-11943. |
入库方式： OAI收割
来源：大连化学物理研究所
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