DABCO-Catalyzed Synthesis of Trifluoromethylated Furans from Propargyl Alcohols and Methyl 2-Perfluoroalkynoate
文献类型：期刊论文
| 作者 | Chong, Qinglei1; Xin, Xiaoyi1; Wang, Chunxiang1; Wu, Fan1; Wang, Haolong1; Shi, Ji-cheng2; Wan, Boshun1 |
| 刊名 | journal of organic chemistry
 |
| 出版日期 | 2014-03-07 |
| 卷号 | 79期号:5页码:2105-2110 |
| 通讯作者 | 施继成 ; 万伯顺 |
| 英文摘要 | the dabco-catalyzed reaction of propargyl alcohols with methyl 2-perfluoroalkynoate to give trifluoromethylated furans in up to 98% yield under mild conditions has been developed. the established allene-enol and control experiments indicate that the reaction should proceed through a michael addition and claisen rearrangement/cyclization process. |
| WOS标题词 | science & technology ; physical sciences |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | functionalized polysubstituted furans ; pot regiospecific synthesis ; claisen rearrangement ; vinyl ethers ; medicinal chemistry ; aromatic-compounds ; domino access ; enol-ethers ; derivatives ; fluorine |
| 收录类别 | SCI ; IC ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000332756500023 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/144266]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Guangdong Univ Petrochem Technol, Coll Chem Engn, Maoming 525000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chong, Qinglei,Xin, Xiaoyi,Wang, Chunxiang,et al. DABCO-Catalyzed Synthesis of Trifluoromethylated Furans from Propargyl Alcohols and Methyl 2-Perfluoroalkynoate[J]. journal of organic chemistry,2014,79(5):2105-2110. |
| APA | Chong, Qinglei.,Xin, Xiaoyi.,Wang, Chunxiang.,Wu, Fan.,Wang, Haolong.,...&Wan, Boshun.(2014).DABCO-Catalyzed Synthesis of Trifluoromethylated Furans from Propargyl Alcohols and Methyl 2-Perfluoroalkynoate.journal of organic chemistry,79(5),2105-2110. |
| MLA | Chong, Qinglei,et al."DABCO-Catalyzed Synthesis of Trifluoromethylated Furans from Propargyl Alcohols and Methyl 2-Perfluoroalkynoate".journal of organic chemistry 79.5(2014):2105-2110. |
入库方式： OAI收割
来源：大连化学物理研究所
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