Enantioselective Cu-catalyzed decarboxylative propargylic amination of propargyl carbamates
文献类型：期刊论文
| 作者 | Zou, Yuan1,2; Zhu, Fu-Lin2; Duan, Zheng-Chao3; Wang, Ya-Hui2; Zhang, De-Yang2; Cao, Zhong1; Zheng, Zhuo2; Hu, Xiang-Ping2 |
| 刊名 | tetrahedron letters
 |
| 出版日期 | 2014-03-19 |
| 卷号 | 55期号:12页码:2033-2036 |
| 关键词 | Copper Asymmetric catalysis Decarboxylation Propargylic amination Propargyl carbamate |
| 通讯作者 | 胡向平 |
| 英文摘要 | a copper-catalyzed asymmetric propargylic amination with a chiral ketimine p,n,n-ligand that proceeds via decarboxylation of propargyl carbamates has been developed. the reaction can be performed under the mild condition for a broad range of substrates, providing the corresponding propargylic amines in high yields and with up to 97% ee. this reaction represents a new and facile access to optically active propargylic amines. (c) 2014 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | substitution-reactions ; carbonyl groups ; amines ; acetates ; esters ; ligands ; imines ; nucleophiles ; additions ; alkynes |
| 收录类别 | SCI ; IC ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000334480700018 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/144319]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Changsha Univ Sci & Technol, Sch Chem & Biol Engn, Changsha 410004, Hunan, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 3.Hubei Univ Nationalities, Sch Chem & Environm Engn, Enshi 445000, Hubei, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zou, Yuan,Zhu, Fu-Lin,Duan, Zheng-Chao,et al. Enantioselective Cu-catalyzed decarboxylative propargylic amination of propargyl carbamates[J]. tetrahedron letters,2014,55(12):2033-2036. |
| APA | Zou, Yuan.,Zhu, Fu-Lin.,Duan, Zheng-Chao.,Wang, Ya-Hui.,Zhang, De-Yang.,...&Hu, Xiang-Ping.(2014).Enantioselective Cu-catalyzed decarboxylative propargylic amination of propargyl carbamates.tetrahedron letters,55(12),2033-2036. |
| MLA | Zou, Yuan,et al."Enantioselective Cu-catalyzed decarboxylative propargylic amination of propargyl carbamates".tetrahedron letters 55.12(2014):2033-2036. |
入库方式： OAI收割
来源：大连化学物理研究所
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