Preparation and size-dependent magnetism of highly dispersed iron silicide nanoparticles on silica
文献类型:期刊论文
作者 | Guan, Jingchao1; Chen, Xiao1; Yang, Kaixuan1; Rykov, Alexandre2; Wang, Junhu2; Liang, Changhai1 |
刊名 | journal of materials chemistry c
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出版日期 | 2014-07-21 |
卷号 | 2期号:27页码:5292-5298 |
通讯作者 | changhailiang |
英文摘要 | fe3si nanoparticles with a size of about 6-9 nm well dispersed on silica have been prepared by pyrolysis of ferrocene-polydimethylsilane composites at 600 degrees c. powder xrd patterns, tem and hrtem images, and xps spectra revealed that the average particle size increased with increasing pyrolysis temperature and a new phase, fe5si3, appeared when the pyrolysis temperature was above 800 degrees c. fe-57 mossbauer spectra, m - h curves and fc and zfc curves demonstrated that the as-prepared nanoparticles presented superparamagnetic behavior at 27 degrees c and ferromagnetic behavior at -268 degrees c, and their particle sizes had a great impact on their magnetic properties. the fe3si nanoparticles on silica may find applications in magnetically recording materials, magnetically separable catalysts and electrode materials for spintronic devices. |
WOS标题词 | science & technology ; technology ; physical sciences |
学科主题 | 物理化学 |
类目[WOS] | materials science, multidisciplinary ; physics, applied |
研究领域[WOS] | materials science ; physics |
关键词[WOS] | thin-films ; fe3si ; particles ; nanowires ; fe5si3 ; intermetallics ; temperature ; deposition ; pyrolysis ; transport |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000338601800006 |
公开日期 | 2016-05-09 |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/144326] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Dalian Univ Technol, Sch Chem Engn, Lab Adv Mat & Catalyt Engn, Dalian 116024, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Mossbauer Effect Data Ctr, Dalian 116024, Peoples R China |
推荐引用方式 GB/T 7714 | Guan, Jingchao,Chen, Xiao,Yang, Kaixuan,et al. Preparation and size-dependent magnetism of highly dispersed iron silicide nanoparticles on silica[J]. journal of materials chemistry c,2014,2(27):5292-5298. |
APA | Guan, Jingchao,Chen, Xiao,Yang, Kaixuan,Rykov, Alexandre,Wang, Junhu,&Liang, Changhai.(2014).Preparation and size-dependent magnetism of highly dispersed iron silicide nanoparticles on silica.journal of materials chemistry c,2(27),5292-5298. |
MLA | Guan, Jingchao,et al."Preparation and size-dependent magnetism of highly dispersed iron silicide nanoparticles on silica".journal of materials chemistry c 2.27(2014):5292-5298. |
入库方式: OAI收割
来源:大连化学物理研究所
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