Efficient oxidation of ethylbenzene catalyzed by cobalt zeolitic imidazolate framework ZIF-67 and NHPI
文献类型：期刊论文
| 作者 | Li, Hongyan1,2; Ma, Hong2; Wang, Xinhong1; Gao, Jin2; Chen, Chen2; Shi, Song2; Qu, Minjie1; Feng, Na1; Xu, Jie2 |
| 刊名 | journal of energy chemistry
 |
| 出版日期 | 2014-11-01 |
| 卷号 | 23期号:6页码:742-746 |
| 关键词 | N-hydroxyphthalimide ZIF-67 oxidation ethylbenzene acetophenone |
| 通讯作者 | 徐杰 |
| 英文摘要 | efficient catalytic oxidation of ethylbenzene to acetophenone was realized using the catalytic system of cobalt zeolitic imidazolate framework zif-67/n-hydroxyphthalimide (nhpi) under mild conditions. 95.2% conversion of ethylbenzene with 90.3% selectivity to acetophenone could be obtained at 373 k under 0.3 mpa o(2) for 9 h. the results show that there exists synergetic effect between zif-67 and nhpi. 1-phenylethyl hydroperoxide (pehp) was generated via a radical process involving the hydrogen abstraction from ethylbenzene by phthalimide n-oxyl, and subsequently effectively decomposed to acetophenone by zif-67. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; energy & fuels ; engineering, chemical |
| 研究领域[WOS] | chemistry ; energy & fuels ; engineering |
| 关键词[WOS] | room-temperature synthesis ; n-hydroxyphthalimide nhpi ; molecular-oxygen ; selective oxidation ; aerobic oxidation ; carbon nanotubes ; combination ; performance ; hydrocarbon |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000346331100009 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/144367]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Dalian Polytech Univ, Sch Text & Mat Engn, Dalian 116034, Liaoning, Peoples R China 2.Chinese Acad Sci, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Hongyan,Ma, Hong,Wang, Xinhong,et al. Efficient oxidation of ethylbenzene catalyzed by cobalt zeolitic imidazolate framework ZIF-67 and NHPI[J]. journal of energy chemistry,2014,23(6):742-746. |
| APA | Li, Hongyan.,Ma, Hong.,Wang, Xinhong.,Gao, Jin.,Chen, Chen.,...&Xu, Jie.(2014).Efficient oxidation of ethylbenzene catalyzed by cobalt zeolitic imidazolate framework ZIF-67 and NHPI.journal of energy chemistry,23(6),742-746. |
| MLA | Li, Hongyan,et al."Efficient oxidation of ethylbenzene catalyzed by cobalt zeolitic imidazolate framework ZIF-67 and NHPI".journal of energy chemistry 23.6(2014):742-746. |
入库方式： OAI收割
来源：大连化学物理研究所
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