Asymmetric Epoxidation of Olefins with Hydrogen Peroxide by an in Situ-Formed Manganese Complex
文献类型：期刊论文
| 作者 | Dai, Wen1,2,3; Shang, Sensen1,2,3; Chen, Bo1,2,3; Li, Guosong1,2,3; Wang, Lianyue1,2; Ren, Lanhui1,2,3; Gao, Shuang1,2 |
| 刊名 | journal of organic chemistry
 |
| 出版日期 | 2014-07-18 |
| 卷号 | 79期号:14页码:6688-6694 |
| 通讯作者 | 高爽 |
| 英文摘要 | asymmetric epoxidation of a variety of cis, trans, terminal, and trisubstituted olefins in excellent yields (up to 94%) and enantioselectivities (>99% cc) by an in situ-formed manganese complex using h2o2 has been developed. a relationship between the hydrophobicity of the catalyst imposed by ligand and the catalytic activity has been observed. the influence of the amount and identity of the acid additive was examined, and improved enantioselectivities were achieved through the use of a catalytic amount of a carboxylic acid additive. |
| WOS标题词 | science & technology ; physical sciences |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | electron-deficient olefins ; nonheme iron catalysts ; enantioselective epoxidation ; system hydrogen ; terminal olefins ; (l=1,4,7-trimethyl-1,4,7-triazacyclononane)-oxalic acid ; stereoselective epoxidation ; oxidation catalysis ; porphyrin catalyst ; carboxylic acid |
| 收录类别 | SCI ; IC ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000339368300029 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/144381]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Dai, Wen,Shang, Sensen,Chen, Bo,et al. Asymmetric Epoxidation of Olefins with Hydrogen Peroxide by an in Situ-Formed Manganese Complex[J]. journal of organic chemistry,2014,79(14):6688-6694. |
| APA | Dai, Wen.,Shang, Sensen.,Chen, Bo.,Li, Guosong.,Wang, Lianyue.,...&Gao, Shuang.(2014).Asymmetric Epoxidation of Olefins with Hydrogen Peroxide by an in Situ-Formed Manganese Complex.journal of organic chemistry,79(14),6688-6694. |
| MLA | Dai, Wen,et al."Asymmetric Epoxidation of Olefins with Hydrogen Peroxide by an in Situ-Formed Manganese Complex".journal of organic chemistry 79.14(2014):6688-6694. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。