Influences of Si/Al Ratios on the Mesopore Distributions of Hierarchical MFI Zeolites Synthesized by Organosilane Surfactant
文献类型：期刊论文
| 作者 | Yu, Lili1,2; Huang, Shengjun1; Miao, Shu1; Zhu, Gangue1; Zhang, Shuang1; Liu, Zhenni1; Xin, Wenjie1; Xie, Sujuan1; Xu, Longya1 |
| 刊名 | industrial & engineering chemistry research
 |
| 出版日期 | 2014-01-15 |
| 卷号 | 53期号:2页码:693-700 |
| 通讯作者 | 黄声骏 ; 徐龙伢 |
| 英文摘要 | the silicon/aluminum ratio is proved to be a key parameter for mesoporosity tuning in the synthesis of hierarchical mfi zeolites by organosilane surfactant. at the fixed synthesis temperature, the mesopore size distribution evolves from a bimodal type to a uniform mode with the increase of si/al ratios. moreover, different si/al ratios result in opposite responses of mesopore distributions to the elevation of synthesis temperature. with the elevated temperature from 140 to 150 degrees c, the mesopore distribution of low-silica mfi zeolites (si/al-gel = 20) evolves from a bimodal type (centered at 4 and 10 nm) to a relatively uniform mode (centered at 8 nm), whereas the high-silica samples (si/al-gel = 40) exhibit a reverse transformation from a uniform mesopore distribution (centered at 3 nm) to a bimodal mode (centered at 4 and 20 nm). this work demonstrates alternative methods for the mesoporosity tuning of organosilane-directed hierarchical zeolites. |
| WOS标题词 | science & technology ; technology |
| 学科主题 | 物理化学 |
| 类目[WOS] | engineering, chemical |
| 研究领域[WOS] | engineering |
| 关键词[WOS] | nmr ; ir ; composites ; catalyst |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000330018500023 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/144397]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu, Lili,Huang, Shengjun,Miao, Shu,et al. Influences of Si/Al Ratios on the Mesopore Distributions of Hierarchical MFI Zeolites Synthesized by Organosilane Surfactant[J]. industrial & engineering chemistry research,2014,53(2):693-700. |
| APA | Yu, Lili.,Huang, Shengjun.,Miao, Shu.,Zhu, Gangue.,Zhang, Shuang.,...&Xu, Longya.(2014).Influences of Si/Al Ratios on the Mesopore Distributions of Hierarchical MFI Zeolites Synthesized by Organosilane Surfactant.industrial & engineering chemistry research,53(2),693-700. |
| MLA | Yu, Lili,et al."Influences of Si/Al Ratios on the Mesopore Distributions of Hierarchical MFI Zeolites Synthesized by Organosilane Surfactant".industrial & engineering chemistry research 53.2(2014):693-700. |
入库方式： OAI收割
来源：大连化学物理研究所
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