Catalytic conversion of carbohydrates to 5-hydroxymethylfurfural promoted by metal halides
文献类型：期刊论文
| 作者 | Ren, Qiuhe1,2; Huang, Yizheng1; Ma, Hong1; Gao, Jin1; Xu, Jie1 |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2014-04-01 |
| 卷号 | 35期号:4页码:496-500 |
| 关键词 | Carbohydrate 5-Hydroxymethylfurfural Metal halide Catalysis |
| 通讯作者 | 徐杰 |
| 英文摘要 | the promotion effect of alkali metal halides toward the alcl3-catalyzed conversion of glucose to 5-hydroxymethylfurfural (hmf) was investigated. the results show that naf inhibited the reaction. however, nai and nabr promoted the reaction significantly, and the promotion effect of nai was more obvious than that of nabr. in n,n-dimethylacetamide (dmac), when nai was used as an additive for the alcl3-catalyzed conversion of glucose at 130 degrees c for 15 min, glucose conversion increased from 71% to 86%, and the hmf yield increased from 36% to 62%. the alcl3-nai-dmac system could also be used for the catalytic conversion of other carbohydrates such as fructose, mannose, sucrose, maltose, cellobiose, and inulin to hmf. when sucrose was used as the feedstock, a 63% hmf yield was achieved. (c) 2014, dalian institute of chemical physics, chinese academy of sciences. published by elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | aerobic oxidation ; lignocellulosic biomass ; fructose ; glucose ; chemicals ; carbon ; fuels ; 2,5-diformylfuran ; transformation ; salts |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000333781700008 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/144400]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ren, Qiuhe,Huang, Yizheng,Ma, Hong,et al. Catalytic conversion of carbohydrates to 5-hydroxymethylfurfural promoted by metal halides[J]. chinese journal of catalysis,2014,35(4):496-500. |
| APA | Ren, Qiuhe,Huang, Yizheng,Ma, Hong,Gao, Jin,&Xu, Jie.(2014).Catalytic conversion of carbohydrates to 5-hydroxymethylfurfural promoted by metal halides.chinese journal of catalysis,35(4),496-500. |
| MLA | Ren, Qiuhe,et al."Catalytic conversion of carbohydrates to 5-hydroxymethylfurfural promoted by metal halides".chinese journal of catalysis 35.4(2014):496-500. |
入库方式： OAI收割
来源：大连化学物理研究所
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