NH3 Mediated or Ion Migration Reaction: The Case Study on Halide-Amide System
文献类型：期刊论文
| 作者 | Cao, Hujun1,2,3; Wang, Jianhui1; Chua, Yongshen1; Wang, Han1,3; Wu, Guotao1; Xiong, Zhitao1; Qiu, Jieshan2; Chen, Ping1 |
| 刊名 | journal of physical chemistry c
 |
| 出版日期 | 2014-02-06 |
| 卷号 | 118期号:5页码:2344-2349 |
| 通讯作者 | 陈萍 |
| 英文摘要 | lively debates on hydrogen desorption from the amide-hydride system via either ion migration or nh3 mediated mechanisms have been ongoing since the discovery of the amide-hydride system for hydrogen storage. in this work, we employed kinetic analyses to demonstrate that the mechanism of hydrogen desorption depends on the sample morphology and desorption conditions. upon the formation of li amide bromide (li2nh2br), the linh2 unit is confined in the cage of br, resulting in less mobility of ion. hydrogen desorption from the li2nh2br-2lih system appears to follow the nh3 mediated mechanism even if the two starting chemicals have been intensively ball milled. on the other hand, the migrations of li+ and h+ play important roles leading to h-2 formation from the direct combination of h+ (from -nh2) and h- (from lih) when linh2 and lih are intimately in contact. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, physical ; nanoscience & nanotechnology ; materials science, multidisciplinary |
| 研究领域[WOS] | chemistry ; science & technology - other topics ; materials science |
| 关键词[WOS] | hydrogen storage-system ; n-h system ; lithium amide ; mechanism ; hydrides ; imides ; lih ; dehydrogenation ; decomposition ; diffusion |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000331153700014 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/144448]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Dalian Univ Technol, State Key Lab Fine Chem, Liaoning Key Lab Energy Mat & Chem Engn, Carbon Res Lab, Dalian 116024, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cao, Hujun,Wang, Jianhui,Chua, Yongshen,et al. NH3 Mediated or Ion Migration Reaction: The Case Study on Halide-Amide System[J]. journal of physical chemistry c,2014,118(5):2344-2349. |
| APA | Cao, Hujun.,Wang, Jianhui.,Chua, Yongshen.,Wang, Han.,Wu, Guotao.,...&Chen, Ping.(2014).NH3 Mediated or Ion Migration Reaction: The Case Study on Halide-Amide System.journal of physical chemistry c,118(5),2344-2349. |
| MLA | Cao, Hujun,et al."NH3 Mediated or Ion Migration Reaction: The Case Study on Halide-Amide System".journal of physical chemistry c 118.5(2014):2344-2349. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。