Gas separation properties of poly(amide-6-b-ethylene oxide)/amino modified multi-walled carbon nanotubes mixed matrix membranes
文献类型：期刊论文
| 作者 | Zhao, Dan1,2; Ren, Jizhong1; Li, Hui1; Li, Xinxue1; Deng, Maicun1 |
| 刊名 | journal of membrane science
 |
| 出版日期 | 2014-10-01 |
| 卷号 | 467期号:1页码:41-47 |
| 关键词 | Pebax Mixed matrix membranes Multi-walled carbon nanotubes Gas separation |
| 通讯作者 | 任吉中 |
| 英文摘要 | amino modified multi-walled carbon nanotubes (mwnts-nh2) were incorporated into poly(amide-6-b-ethylene oxide) (pebax 1657) to prepare mixed matrix membranes (mmms). the permeation properties of co2, n-2, ch4 and h-2 were studied and the physical properties of pebax/mwnts-nh2 mmms were characterized by x-ray diffractometer (xrd), fourier transform infrared (ftir) and scanning electron microscopy (sem). the incorporation of mwnts-nh2 increased the amorphous region of pebax phase in pebax/mwnts-nh2 mmms, which was beneficial for the improvement of gas permeabilities. the apparent activation energy for permeation (e-p) for co2 decreased with the increase of pressure, while those for n-2, ch4 and h-2 almost did not change. the e-p for co2, n-2, ch4 and h-2 slightly decreased with the incorporation of mwnts-nh2. compared with pristine pebax membrane, co2 permeability increased almost 3 times for pebax/mwnts-nh2 mmms with 33 wt% mwnts-nh2. with the increase of mwnts-nh2 content, the normalized permeabilities of n-2, ch4 and co2 showed almost the same increment and the selectivities of co2/n-2, co2/h-2 and co2/ch4 remained constant, which were consistent with the maxwell model prediction. thus, the incorporation of mwnts-nh2 significantly improved the gas permeation properties of pebax/mwnts-nh2 mmms. (c) 2014 elsevier b.v. all rights reserved. |
| 学科主题 | 物理化学 |
| WOS标题词 | science & technology ; technology ; physical sciences |
| 类目[WOS] | engineering, chemical ; polymer science |
| 研究领域[WOS] | engineering ; polymer science |
| 关键词[WOS] | glycol blend membranes ; co2 separation ; mechanical-properties ; permeation properties ; transport-properties ; composite membranes ; inorganic fillers ; dioxide ; nanocomposites ; permeability |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000340315300005 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/144534]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Dan,Ren, Jizhong,Li, Hui,et al. Gas separation properties of poly(amide-6-b-ethylene oxide)/amino modified multi-walled carbon nanotubes mixed matrix membranes[J]. journal of membrane science,2014,467(1):41-47. |
| APA | Zhao, Dan,Ren, Jizhong,Li, Hui,Li, Xinxue,&Deng, Maicun.(2014).Gas separation properties of poly(amide-6-b-ethylene oxide)/amino modified multi-walled carbon nanotubes mixed matrix membranes.journal of membrane science,467(1),41-47. |
| MLA | Zhao, Dan,et al."Gas separation properties of poly(amide-6-b-ethylene oxide)/amino modified multi-walled carbon nanotubes mixed matrix membranes".journal of membrane science 467.1(2014):41-47. |
入库方式： OAI收割
来源：大连化学物理研究所
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