Synthesis of diesel range alkanes with 2-methylfuran and mesityl oxide from lignocellulose
文献类型：期刊论文
| 作者 | Li, Shanshan1,2; Li, Ning1; Li, Guangyi1,2; Wang, Aiqin1; Cong, Yu1; Wang, Xiaodong1; Zhang, Tao1 |
| 刊名 | catalysis today
 |
| 出版日期 | 2014-10-01 |
| 卷号 | 234期号:1页码:91-99 |
| 关键词 | Solid acid Carbide Renewable diesel 2-Methylfuran Mesityl oxide |
| 通讯作者 | 李宁 |
| 英文摘要 | for the first time, the alkylation of 2-methylfuran with mesityl oxide was carried out over a series of solid acid catalysts. among the investigated candidates, nafion-212 resin exhibited the highest catalytic efficiency and good stability, which can be rationalized by the higher acid strength of this catalyst. the hydrodeoxygenation (hdo) of the alkylation products of 2-methylfuran with mesityl oxide was also studied. ni-mo2c/sio2 and ni-w2c/sio2 were firstly used for the hdo of biomass derived oxygenates and demonstrated excellent catalytic performance for the conversion of the alkylation products to alkanes. compared with ni-w2c/sio2, ni-mo2c/sio2 exhibited higher selectivity to diesel range alkanes. over the ni-mo2c/sio2 catalyst, high carbon yield of diesel range alkanes (77%) could be achieved by the hdo of the alkylation products of 2-methylfuran and mesityl oxide at 573 k and 6.0 mpa h-2. this value is evidently higher than those obtained over noble metal catalysts and ni-wxc/ac under the same reaction conditions. (c) 2014 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 学科主题 | 物理化学 |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | high-quality diesel ; tolerant solid acid ; one-pot conversion ; catalytic conversion ; transportation fuels ; zirconium-phosphate ; tungsten carbides ; reaction pathways ; renewable diesel ; ethylene-glycol |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000339132900011 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/144535]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Shanshan,Li, Ning,Li, Guangyi,et al. Synthesis of diesel range alkanes with 2-methylfuran and mesityl oxide from lignocellulose[J]. catalysis today,2014,234(1):91-99. |
| APA | Li, Shanshan.,Li, Ning.,Li, Guangyi.,Wang, Aiqin.,Cong, Yu.,...&Zhang, Tao.(2014).Synthesis of diesel range alkanes with 2-methylfuran and mesityl oxide from lignocellulose.catalysis today,234(1),91-99. |
| MLA | Li, Shanshan,et al."Synthesis of diesel range alkanes with 2-methylfuran and mesityl oxide from lignocellulose".catalysis today 234.1(2014):91-99. |
入库方式： OAI收割
来源：大连化学物理研究所
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