Promoted role of Cu(NO3)(2) on aerobic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran over VOSO4
文献类型：期刊论文
| 作者 | Jia, Xiuquan1,2; Ma, Jiping1; Wang, Min1; Du, Zhongtian1; Lu, Fang1; Wang, Feng1; Xu, Jie1 |
| 刊名 | applied catalysis a-general
 |
| 出版日期 | 2014-07-22 |
| 卷号 | 482页码:231-236 |
| 关键词 | Catalysis Copper nitrate 2 Oxidation Sustainable chemistry 5-Diformylfuran |
| 英文摘要 | the promoted effect of cu(no3)(2) on aerobic oxidation of 5-hydroxymethylfurfural (hmf) to 2,5-diformylfuran (dff) catalyzed by voso4 in acetonitrile was intensively investigated. it was revealed that cu(no3)(2) facilitated the activation of voso4 to generate active v5+ species via the generation of no gas. the high off selectivity is ascribed to cu2+ cation which can effectively prohibit oxidative c-c bond cleavage reaction of hmf and prevent radical reaction of off to humins. in addition, the polarity of solvent plays a great role on high selectivity of off. (c) 2014 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; life sciences & biomedicine |
| 类目[WOS] | chemistry, physical ; environmental sciences |
| 研究领域[WOS] | chemistry ; environmental sciences & ecology |
| 关键词[WOS] | selective oxidation ; one-pot ; lignocellulosic biomass ; catalytic conversion ; renewable resources ; supported ruthenium ; molecular-oxygen ; vanadyl sulfate ; mild conditions ; alkyl radicals |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000340306500028 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145401]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jia, Xiuquan,Ma, Jiping,Wang, Min,et al. Promoted role of Cu(NO3)(2) on aerobic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran over VOSO4[J]. applied catalysis a-general,2014,482:231-236. |
| APA | Jia, Xiuquan.,Ma, Jiping.,Wang, Min.,Du, Zhongtian.,Lu, Fang.,...&Xu, Jie.(2014).Promoted role of Cu(NO3)(2) on aerobic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran over VOSO4.applied catalysis a-general,482,231-236. |
| MLA | Jia, Xiuquan,et al."Promoted role of Cu(NO3)(2) on aerobic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran over VOSO4".applied catalysis a-general 482(2014):231-236. |
入库方式： OAI收割
来源：大连化学物理研究所
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