Photofragment translational spectroscopy at 304 nm from C-H symmetric stretch excited CH3I [v (1)=1]
文献类型：期刊论文
| 作者 | Zhou ZhiMin; Hu LiLi; Dong ChangWu; Zhang LiJuan; Liu Sheng; Du YiKui; Cheng Min1; Zhu QiHe |
| 刊名 | science china-chemistry
 |
| 出版日期 | 2014-06-01 |
| 卷号 | 57期号:6页码:902-910 |
| 关键词 | photodissociation methyl iodide excited vibrational state photofragment translational spectrum (PTS) |
| 英文摘要 | the 304 nm photodissociation of the c-h symmetric stretch excited ch3i [v (1) = 1, v (2) = 0] (v (1) denotes the c-h symmetric stretch mode, and v (2) denotes the umbrella mode) is studied with our simple photofragment translational spectrometer. an ir laser is used to excite the ground state ch3i [0, 0] to the c-h symmetric stretch excited ch3i [1, 0]. with ir laser off and on, the fractions of photofragments ch3 (nu (1), nu (2)) from the 304 nm photodissociation of ch3i [1, 0] have been determined through the photofragment translational spectra (pts) from measuring i and i* and also through the pts from measuring ch3 (0, 0) (1, 0) (0, 1) and (1, 1). the experimental results show that the c-h symmetric stretch vibration (v (1) = 1) in parent molecules is about 66% retained in the photofragments in the i channel, but only 24% in the i* channel. the populations of photofragments ch3 (0, 2) and (0, 3) are higher than ch3 (0, 0) and (0, 1), showing strong inverted population both in i and i* channels. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | methyl-iodide ; ab-initio ; photodissociation ; dynamics ; energy ; band ; resolution ; star |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000336747700015 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145413]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, State Key Lab Mol React Dynam, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou ZhiMin,Hu LiLi,Dong ChangWu,et al. Photofragment translational spectroscopy at 304 nm from C-H symmetric stretch excited CH3I [v (1)=1][J]. science china-chemistry,2014,57(6):902-910. |
| APA | Zhou ZhiMin.,Hu LiLi.,Dong ChangWu.,Zhang LiJuan.,Liu Sheng.,...&Zhu QiHe.(2014).Photofragment translational spectroscopy at 304 nm from C-H symmetric stretch excited CH3I [v (1)=1].science china-chemistry,57(6),902-910. |
| MLA | Zhou ZhiMin,et al."Photofragment translational spectroscopy at 304 nm from C-H symmetric stretch excited CH3I [v (1)=1]".science china-chemistry 57.6(2014):902-910. |
入库方式： OAI收割
来源：大连化学物理研究所
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