Communication: Imaging the effects of the antisymmetric-stretching excitation in the O(P-3) + CH4(v(3)=1) reaction
文献类型：期刊论文
| 作者 | Pan, Huilin1,2; Liu, Kopin1 |
| 刊名 | journal of chemical physics
 |
| 出版日期 | 2014-05-21 |
| 卷号 | 140期号:19 |
| 英文摘要 | effects of one-quantum excitation of the antisymmetric-stretching mode of ch4(v(3) = 1) on the o(p-3) + ch4 reaction were studied in a crossed-beam, ion-imaging experiment. in the post-threshold region, we found that (1) the product state distributions are dominated by the ch3(0(0)) + oh(v' = 1) pair, (2) the product angular distributions extend toward sideways from the backward dominance of the ground-state reaction, and (3) vibrational excitation exerts a positive effect on reactivity, but translational energy is more efficient in promoting the rate of this central-barrier reaction. all major findings agree reasonably well with recent theoretical results. some remaining questions are pointed out. (c) 2014 aip publishing llc. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | physics, atomic, molecular & chemical |
| 研究领域[WOS] | physics |
| 关键词[WOS] | potential-energy surface ; thermal rate constants ; quantum dynamics ; vibrational excitations ; mode selectivity ; crossed-beams ; f atom ; methane ; reactivity ; bond |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000336832700001 |
| 公开日期 | 2016-05-09 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/145458]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Acad Sinica, IAMS, Taipei 10617, Taiwan 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Pan, Huilin,Liu, Kopin. Communication: Imaging the effects of the antisymmetric-stretching excitation in the O(P-3) + CH4(v(3)=1) reaction[J]. journal of chemical physics,2014,140(19). |
| APA | Pan, Huilin,&Liu, Kopin.(2014).Communication: Imaging the effects of the antisymmetric-stretching excitation in the O(P-3) + CH4(v(3)=1) reaction.journal of chemical physics,140(19). |
| MLA | Pan, Huilin,et al."Communication: Imaging the effects of the antisymmetric-stretching excitation in the O(P-3) + CH4(v(3)=1) reaction".journal of chemical physics 140.19(2014). |
入库方式： OAI收割
来源：大连化学物理研究所
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